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The crystal structure was determined on the basis of single crystal X\u2010ray diffraction data, to reveal the hexagonal space group <jats:italic>P<\/jats:italic>6<jats:sub>3<\/jats:sub> with <jats:italic>a<\/jats:italic>=885.2(2), <jats:italic>c<\/jats:italic>=716.72(8) pm, <jats:italic>Z<\/jats:italic>=8, <jats:italic>R<\/jats:italic><jats:sub>1<\/jats:sub>=0.0178, and <jats:italic>wR<\/jats:italic><jats:sub>2<\/jats:sub>=0.0388 (all data). CdB<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> is built up from interconnected layers of BO<jats:sub>4<\/jats:sub>\u2010tetrahedra and exhibits for the first time the basic structure of a family of compounds, represented by BaGa<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>, KAlSiO<jats:sub>4<\/jats:sub>, KGeAlO<jats:sub>4<\/jats:sub>, KCoPO<jats:sub>4<\/jats:sub>, CaP<jats:sub>2<\/jats:sub>N<jats:sub>4<\/jats:sub> and the recently discovered SrP<jats:sub>2<\/jats:sub>N<jats:sub>4<\/jats:sub>. The lack of superstructure ordering in CdB<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> was confirmed by electron diffraction. Additionally, a B\uf8ffO\uf8ffB angle of 180\u00b0 was found in this borate for the first time.<\/jats:p>","DOI":"10.1002\/chem.200800506","type":"journal-article","created":{"date-parts":[[2008,6,3]],"date-time":"2008-06-03T10:26:50Z","timestamp":1212488810000},"page":"6149-6154","source":"Crossref","is-referenced-by-count":23,"title":["Synthesis and Crystal Structure of the New High\u2010Pressure Phase CdB<sub>2<\/sub>O<sub>4<\/sub>"],"prefix":"10.1002","volume":"14","author":[{"given":"Johanna\u2005S.","family":"Knyrim","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Holger","family":"Emme","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Markus","family":"D\u00f6blinger","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oliver","family":"Oeckler","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matthias","family":"Weil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hubert","family":"Huppertz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2008,7,4]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.2002.9583"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200470052"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200400202"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2006.03.002"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-2007-0602"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2007.09.004"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1293-2558(02)00057-2"},{"key":"e_1_2_6_8_2","doi-asserted-by":"crossref","first-page":"257","DOI":"10.1515\/znb-2003-0403","volume":"58","author":"Huppertz H.","year":"2003","journal-title":"Z. 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