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The reaction of oxygen with <jats:bold>1<\/jats:bold> at room temperature forms a paramagnetic derivative [Sn(isq)<jats:sub>2<\/jats:sub>Ph<jats:sub>2<\/jats:sub>] (<jats:bold>3<\/jats:bold>) (isq=radical anion of ImQ) and diphenyltin(IV) oxide [{Ph<jats:sub>2<\/jats:sub>SnO}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>]. Interaction of <jats:bold>1<\/jats:bold> with sulfur gives another monophenyl\u2010substituted paramagnetic tin(IV) complex, [Sn(ap)(isq)Ph] (<jats:bold>4<\/jats:bold>), and the sulfide, [Ph<jats:sub>3<\/jats:sub>Sn]<jats:sub>2<\/jats:sub>S. The oxidation of <jats:bold>2<\/jats:bold> with oxygen and with sulfur proceeds through the derivative [Sn(isq)<jats:sub>2<\/jats:sub>Et<jats:sub>2<\/jats:sub>] (<jats:bold>7<\/jats:bold>), which undergoes alkyl elimination to give two new tin(IV) compounds, [Sn(ap)(isq)Et] (<jats:bold>5<\/jats:bold>) and [Sn(ap)(EtImQ)Et] (<jats:bold>6<\/jats:bold>) (EtImQ=2,4\u2010di\u2010<jats:italic>tert<\/jats:italic>\u2010butyl\u20106\u2010(2,6\u2010diisopropylphenylimino)\u20103\u2010ethylcyclohexa\u20101,4\u2010dienolate ligand), respectively, along with the corresponding alkyltin(IV) oxide and sulfide. Complexes <jats:bold>3<\/jats:bold>\u2013<jats:bold>5<\/jats:bold> and <jats:bold>7<\/jats:bold> were studied by EPR spectroscopy. The structures of <jats:bold>3<\/jats:bold>, <jats:bold>4<\/jats:bold> and <jats:bold>6<\/jats:bold> were investigated by X\u2010ray analysis.<\/jats:p>","DOI":"10.1002\/chem.200801203","type":"journal-article","created":{"date-parts":[[2008,9,11]],"date-time":"2008-09-11T04:39:14Z","timestamp":1221107954000},"page":"10085-10093","source":"Crossref","is-referenced-by-count":36,"title":["Oxidation by Oxygen and Sulfur of Tin(IV) Derivatives Containing a Redox\u2010Active <i>o<\/i>\u2010Amidophenolate Ligand"],"prefix":"10.1002","volume":"14","author":[{"given":"Alexandr\u2005V.","family":"Piskunov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina\u2005N.","family":"Mescheryakova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Georgii\u2005K.","family":"Fukin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Evgenii\u2005V.","family":"Baranov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Markus","family":"Hummert","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrei\u2005S.","family":"Shavyrin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vladimir\u2005K.","family":"Cherkasov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gleb\u2005A.","family":"Abakumov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2008,10,30]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200500860"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400948"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500330"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200352200"},{"key":"e_1_2_6_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200352200"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400973"},{"key":"e_1_2_6_7_2","unstructured":"\u00a0"},{"key":"e_1_2_6_8_2","first-page":"7786","volume":"128","author":"Tumanskii B.","year":"2006","journal-title":"J. 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