{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:10:43Z","timestamp":1760296243186,"version":"build-2065373602"},"reference-count":33,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2009,5,28]],"date-time":"2009-05-28T00:00:00Z","timestamp":1243468800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2009,7,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p><jats:bold>Although free from structural disorder<\/jats:bold>, the new intermetallic compound Cd<jats:sub>13\u2212<jats:italic>x<\/jats:italic><\/jats:sub>In<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Sb<jats:sub>10<\/jats:sub> (see figure) displays similarly low thermal conductivity values as disordered thermoelectric \u03b2\u2010Zn<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub> with an isostructural framework.<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mcontent.gif\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p><jats:p>Cd<jats:sub>13\u2212<jats:italic>x<\/jats:italic><\/jats:sub>In<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Sb<jats:sub>10<\/jats:sub> (<jats:italic>x<\/jats:italic>\u22482.7, <jats:italic>y<\/jats:italic>\u22481.5) was synthesized in the form of mm\u2010sized crystals from reaction mixtures containing excess cadmium. The intermetallic compound crystallizes in the rhombohedral space group <jats:italic>R<\/jats:italic><jats:styled-content>$\\bar 3$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content><jats:italic>m<\/jats:italic> with <jats:italic>a<\/jats:italic>=12.9704(4), <jats:italic>c<\/jats:italic>=12.9443(5)\u2005\u00c5, <jats:italic>V<\/jats:italic>=1886.0(1)\u2005\u00c5<jats:sup>3<\/jats:sup>, <jats:italic>Z<\/jats:italic>=3 and is isostructural to thermoelectric \u03b2\u2010Zn<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub> and \u03b2\u2010Cd<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub>. However, in contrast to these last two compounds Cd<jats:sub>13\u2212<jats:italic>x<\/jats:italic><\/jats:sub>In<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Sb<jats:sub>10<\/jats:sub> is free from interstitial atoms and does not display any temperature polymorphism. The electrical resistivity of Cd<jats:sub>13\u2212<jats:italic>x<\/jats:italic><\/jats:sub>In<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Sb<jats:sub>10<\/jats:sub> is considerably higher than that of Zn<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub> and Cd<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub> although the temperature behavior remains that of a metal. The thermal conductivity of Cd<jats:sub>13\u2212<jats:italic>x<\/jats:italic><\/jats:sub>In<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Sb<jats:sub>10<\/jats:sub> is low, with room\u2010temperature magnitudes around 0.8\u2005W\u2009m<jats:sup>\u22121<\/jats:sup>\u2009K<jats:sup>\u22121<\/jats:sup>, which is comparable to disordered or complex structured Cd<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub> and Zn<jats:sub>4<\/jats:sub>Sb<jats:sub>3<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/chem.200802695","type":"journal-article","created":{"date-parts":[[2009,5,28]],"date-time":"2009-05-28T10:40:52Z","timestamp":1243507252000},"page":"6704-6710","source":"Crossref","is-referenced-by-count":4,"title":["Cd<sub>13\u2212<i>x<\/i><\/sub>In<sub><i>y<\/i><\/sub>Sb<sub>10<\/sub> (<i>x<\/i>\u22482.7, <i>y<\/i>\u22481.5): An Interstitial\u2010Free Variant of Thermoelectric \u03b2\u2010Zn<sub>4<\/sub>Sb<sub>3<\/sub>"],"prefix":"10.1002","volume":"15","author":[{"given":"Andreas","family":"Teng\u00e5","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sven","family":"Lidin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jean\u2010Philippe","family":"Belieres","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nathan","family":"Newman","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yang","family":"Wu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ulrich","family":"H\u00e4ussermann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2009,6,29]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-3697(96)00228-4"},{"key":"e_1_2_6_2_2","first-page":"407","volume-title":"CRC Handbook of Thermoelectrics","author":"Slack G. A.","year":"1995"},{"volume-title":"Solid State Physics, Vol.\u200551","year":"1998","author":"Mahan G. D.","key":"e_1_2_6_3_2"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.342976"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1154"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200400327"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.99.125501"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1557\/mrs2006.45"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja805454p"},{"key":"e_1_2_6_10_2","unstructured":"\u00a0"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.intermet.2004.02.030"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/40\/16\/033"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm702247b"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.2946450"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.3037203"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.2000.8790"},{"key":"e_1_2_6_17_2","unstructured":"CrysAlis Software for automated data collection and reduction Oxford Diffraction 2006."},{"key":"e_1_2_6_18_2","unstructured":"V. Petricek M. Dusek The Crystallographic Computing System JANA2000 Institute of Physics Praha (Czech Republic) 2000."},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(78)90109-1"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2007.07.013"},{"volume-title":"Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys, Volume\u2005IV\/5c","year":"1993","author":"Predel B.","key":"e_1_2_6_21_2"},{"volume-title":"Smithells Metals Reference Book","year":"2004","key":"e_1_2_6_22_2"},{"key":"e_1_2_6_23_2","first-page":"1708","volume":"13","author":"Psarev V. I.","year":"1977","journal-title":"Inorg. Mater."},{"key":"e_1_2_6_24_2","first-page":"166","volume":"23","author":"Pavlova L. M.","year":"1987","journal-title":"Inorg. Mater."},{"key":"e_1_2_6_25_2","first-page":"654","volume":"33","author":"Kirii V. G.","year":"1997","journal-title":"Inorg. Mater."},{"volume-title":"Binary Alloy Phase Diagrams","year":"1990","author":"Massalski T. S.","key":"e_1_2_6_26_2"},{"key":"e_1_2_6_27_2","unstructured":"Powder X\u2010ray diffraction patterns of the samples after the first and second heating cycle show traces of InSb."},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0629659"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja044980p"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm062384j"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500020"},{"volume-title":"Thermal Conductivity: Theory, Properties and Applications","year":"2004","key":"e_1_2_6_32_2"},{"key":"e_1_2_6_33_2","first-page":"1","volume-title":"Solid State Physics, Vol.\u200534","author":"Slack G. A.","year":"1979"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.200802695","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.200802695","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T18:32:30Z","timestamp":1760293950000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.200802695"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,6,29]]},"references-count":33,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2009,7,6]]}},"alternative-id":["10.1002\/chem.200802695"],"URL":"https:\/\/doi.org\/10.1002\/chem.200802695","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2009,6,29]]}}}