{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,6]],"date-time":"2025-12-06T04:35:57Z","timestamp":1764995757753,"version":"build-2065373602"},"reference-count":108,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2009,6,19]],"date-time":"2009-06-19T00:00:00Z","timestamp":1245369600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2009,7,20]]},"abstract":"Abstract<\/jats:title>Several heterometallic nitrido complexes were prepared by reaction of the imido\u2013nitrido titanium complex [{Ti(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)(\u03bc\u2010NH)}3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)] (1<\/jats:bold>) with amido derivatives of Group\u200513\u201315 elements. Treatment of 1<\/jats:bold> with bis(trimethylsilyl)amido [M{N(SiMe3<\/jats:sub>)2<\/jats:sub>}3<\/jats:sub>] derivatives of aluminum, gallium, or indium in toluene at 150\u2013190\u2009\u00b0C affords the single\u2010cube amidoaluminum complex [{(Me3<\/jats:sub>Si)2<\/jats:sub>N}Al{(\u03bc3<\/jats:sub>\u2010N)2<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}] (2<\/jats:bold>) or the corner\u2010shared double\u2010cube compounds [M(\u03bc3<\/jats:sub>\u2010N)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)3<\/jats:sub>{Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}2<\/jats:sub>] [M=Ga (3<\/jats:bold>), In (4<\/jats:bold>)]. Complexes 3<\/jats:bold> and 4<\/jats:bold> were also obtained by treatment of 1<\/jats:bold> with the trialkyl derivatives [M(CH2<\/jats:sub>SiMe3<\/jats:sub>)3<\/jats:sub>] (M=Ga, In) at high temperatures. The analogous reaction of 1<\/jats:bold> with [{Ga(NMe2<\/jats:sub>)3<\/jats:sub>}2<\/jats:sub>] at 110\u2009\u00b0C leads to [{Ga(\u03bc3<\/jats:sub>\u2010N)2<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}2<\/jats:sub>] (5<\/jats:bold>), in which two [GaTi3<\/jats:sub>N4<\/jats:sub>] cube\u2010type moieties are linked through a gallium\u2013gallium bond. Complex 1<\/jats:bold> reacts with one equivalent of germanium, tin, or lead bis(trimethylsilyl)amido derivatives [M{N(SiMe3<\/jats:sub>)2<\/jats:sub>}2<\/jats:sub>] in toluene at room temperature to give cube\u2010type complexes [M{(\u03bc3<\/jats:sub>\u2010N)2<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}] [M=Ge (6<\/jats:bold>), Sn (7<\/jats:bold>), Pb (8<\/jats:bold>)]. Monitoring the reaction of 1<\/jats:bold> with [Sn{N(SiMe3<\/jats:sub>)2<\/jats:sub>}2<\/jats:sub>] and [Sn(C5<\/jats:sub>H5<\/jats:sub>)2<\/jats:sub>] by NMR spectroscopy allows the identification of intermediates [RSn{(\u03bc3<\/jats:sub>\u2010N)(\u03bc3<\/jats:sub>\u2010NH)2<\/jats:sub>Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}] [R=N(SiMe3<\/jats:sub>)2<\/jats:sub> (9<\/jats:bold>), C5<\/jats:sub>H5<\/jats:sub> (10<\/jats:bold>)] in the formation of 7<\/jats:bold>. Addition of one equivalent of the metalloligand 1<\/jats:bold> to a solution of lead derivative 8<\/jats:bold> or the treatment of 1<\/jats:bold> with a half equivalent of [Pb{N(SiMe3<\/jats:sub>)2<\/jats:sub>}2<\/jats:sub>] afford the corner\u2010shared double\u2010cube compound [Pb(\u03bc3<\/jats:sub>\u2010N)2<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)4<\/jats:sub>{Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}2<\/jats:sub>] (11<\/jats:bold>). Analogous antimony and bismuth derivatives [M(\u03bc3<\/jats:sub>\u2010N)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010NH)3<\/jats:sub>{Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc3<\/jats:sub>\u2010N)}2<\/jats:sub>] [M=Sb (12<\/jats:bold>), Bi (13<\/jats:bold>)] were obtained through the reaction of 1<\/jats:bold> with the tris(dimethylamido) reagents [M(NMe2<\/jats:sub>)3<\/jats:sub>]. Treatment of 1<\/jats:bold> with [AlCl2<\/jats:sub>{N(SiMe3<\/jats:sub>)2<\/jats:sub>}(OEt2<\/jats:sub>)] affords the precipitation of the singular aluminum\u2013titanium square\u2010pyramidal aggregate [{{(Me3<\/jats:sub>Si)2<\/jats:sub>N}Cl3<\/jats:sub>Al2<\/jats:sub>}(\u03bc3<\/jats:sub>\u2010N)(\u03bc3<\/jats:sub>\u2010NH)2<\/jats:sub>{Ti3<\/jats:sub>(\u03b75<\/jats:sup>\u2010C5<\/jats:sub>Me5<\/jats:sub>)3<\/jats:sub>(\u03bc\u2010Cl)(\u03bc3<\/jats:sub>\u2010N)}] (14<\/jats:bold>). The X\u2010ray crystal structures of 5<\/jats:bold>, 11<\/jats:bold>, 13<\/jats:bold>, 14<\/jats:bold>, and [AlCl{N(SiMe3<\/jats:sub>)2<\/jats:sub>}2<\/jats:sub>] were determined.<\/jats:p>","DOI":"10.1002\/chem.200900660","type":"journal-article","created":{"date-parts":[[2009,6,19]],"date-time":"2009-06-19T10:51:59Z","timestamp":1245408719000},"page":"7180-7191","source":"Crossref","is-referenced-by-count":22,"title":["Molecular Nitrides with Titanium and Group 13\u201315 Elements"],"prefix":"10.1002","volume":"15","author":[{"given":"Mar\u00eda","family":"Garc\u00eda\u2010Castro","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Avelino","family":"Mart\u00edn","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Miguel","family":"Mena","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carlos","family":"Y\u00e9lamos","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2009,7,13]]},"reference":[{"volume-title":"Molecular Clusters of the Main Group Elements","year":"2004","key":"e_1_2_6_1_2"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/B0-08-043748-6\/09005-8"},{"key":"e_1_2_6_4_2","first-page":"3121","volume-title":"Encyclopedia of Inorganic Chemistry II, Vol.\u20055","author":"Winter C. H.","year":"2005"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/B0-08-043748-6\/02002-8"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.03.016"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)00126-X"},{"key":"e_1_2_6_8_2","unstructured":"For selected examples of Group\u200513 imido cage compounds see:"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9790001206"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881001213"},{"key":"e_1_2_6_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198816991"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00009a025"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19931050723"},{"key":"e_1_2_6_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199310561"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00104a039"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9607457"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(02)01125-7"},{"key":"e_1_2_6_16_2","unstructured":"For selected examples of Group\u200514 imido cage compounds see:"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00099a001"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00018a005"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9950001991"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic011090r"},{"key":"e_1_2_6_21_2","unstructured":"For selected examples of Group\u200515 imido cage compounds see:"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9940002963"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(97)00372-0"},{"key":"e_1_2_6_24_2","unstructured":"\u00a0"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19810930506"},{"key":"e_1_2_6_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198104133"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19921040805"},{"key":"e_1_2_6_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199209551"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/a802635a"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891010628"},{"key":"e_1_2_6_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198907541"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic9907718"},{"key":"e_1_2_6_30_2","unstructured":"\u00a0"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39950002185"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0001927"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00036a037"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220303"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0004500"},{"key":"e_1_2_6_37_2","first-page":"1","volume":"50","author":"Bai G.","year":"2002","journal-title":"Bull. Pol. Acad. Sci\u2010Chem."},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2004.01.017"},{"key":"e_1_2_6_39_2","unstructured":"\u00a0"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00333a016"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00178a022"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm960034z"},{"key":"e_1_2_6_43_2","unstructured":"\u00a0"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00031a008"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/om950947n"},{"key":"e_1_2_6_46_2","unstructured":"\u00a0"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881001011"},{"key":"e_1_2_6_47_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198813301"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39890000748"},{"key":"e_1_2_6_49_2","unstructured":"\u00a0"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001002)112:19<3602::AID-ANGE3602>3.0.CO;2-3"},{"key":"e_1_2_6_50_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001002)39:19<3460::AID-ANIE3460>3.0.CO;2-Y"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200204593"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic035493y"},{"key":"e_1_2_6_53_2","unstructured":"\u00a0"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000204)112:3<544::AID-ANGE544>3.0.CO;2-N"},{"key":"e_1_2_6_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000204)39:3<534::AID-ANIE534>3.0.CO;2-3"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010903)7:17<3644::AID-CHEM3644>3.0.CO;2-9"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200400553"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060895"},{"key":"e_1_2_6_58_2","unstructured":"\u00a0"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39840001453"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(91)80254-H"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270193000484"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)05040-I"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(97)00544-5"},{"key":"e_1_2_6_64_2","unstructured":"\u00a0"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39870000858"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(88)87076-1"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010202)7:3<647::AID-CHEM647>3.0.CO;2-A"},{"key":"e_1_2_6_68_2","unstructured":"A singlet at\u03b4=2.17\u2005ppm could be tentatively assigned to tetramethylhydrazine Me2NNMe2."},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/om950812h"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200206)628:6<1319::AID-ZAAC1319>3.0.CO;2-S"},{"key":"e_1_2_6_71_2","unstructured":"\u00a0"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00124a050"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0103310"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/b212144c"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2005.10.020"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200700736"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1975-9-1006"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)80578-1"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)80797-4"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00093a010"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80441-5"},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/b503405a"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00101a016"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic961030z"},{"key":"e_1_2_6_85_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0100121"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00028a026"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1080\/02603599908020413"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1039\/b705202b"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00346a018"},{"key":"e_1_2_6_90_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19971300805"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50206a046"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470132623.ch15"},{"volume-title":"Synthetic Methods of Organometallic and Inorganic Chemistry, Vol.\u20052","year":"1996","author":"Auner N.","key":"e_1_2_6_93_2"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50151a049"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)86892-8"},{"key":"e_1_2_6_96_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39940001481"},{"key":"e_1_2_6_97_2","first-page":"257","volume-title":"Inorganic Experiments","author":"Roesky H. W.","year":"1994"},{"key":"e_1_2_6_98_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889899006020"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767389011189"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.200900660","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.200900660","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:36:44Z","timestamp":1760297804000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.200900660"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,7,13]]},"references-count":108,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2009,7,20]]}},"alternative-id":["10.1002\/chem.200900660"],"URL":"https:\/\/doi.org\/10.1002\/chem.200900660","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2009,7,13]]}}}