{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T13:04:14Z","timestamp":1790514254134,"version":"4.1.0"},"reference-count":153,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2009,11,20]],"date-time":"2009-11-20T00:00:00Z","timestamp":1258675200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2010,1,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Silicon\u2010 and tin\u2010containing molecules are versatile building blocks in organic synthesis. A stalwart method for their preparation relies on the stoichiometric use of silicon\u2010 and tin\u2010based cuprates, although a few copper(I)\u2010catalyzed or even copper\u2010free protocols have been known for decades. In this Concept, we describe our efforts towards copper(I)\u2010catalyzed carbon\uf8ffsilicon and also carbon\uf8fftin bond formations using soft bis(triorganosilyl) and bis(triorganostannyl) zinc reagents as powerful sources of nucleophilic silicon and tin. Conjugate addition, allylic substitution, and carbon\uf8ffcarbon multiple bond functionalization is now catalytic in copper!<\/jats:p>","DOI":"10.1002\/chem.200902222","type":"journal-article","created":{"date-parts":[[2009,11,20]],"date-time":"2009-11-20T13:17:16Z","timestamp":1258723036000},"page":"402-412","source":"Crossref","is-referenced-by-count":89,"title":["Silicon\u2010 and Tin\u2010Based Cuprates: Now Catalytic in Copper!"],"prefix":"10.1002","volume":"16","author":[{"given":"Andreas","family":"Weickgenannt","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Oestreich","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2009,12,28]]},"reference":[{"key":"e_1_2_7_1_2","volume-title":"Metal\u2010catalyzed Cross\u2010coupling Reactions","year":"2004"},{"key":"e_1_2_7_2_2","unstructured":"\u00a0"},{"key":"e_1_2_7_3_2","first-page":"665","volume-title":"Organometallics in Synthesis: A Manual","author":"Lipshutz B. 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