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The reaction of Me<jats:sub>3<\/jats:sub>PbCl and Ga(ddp) afforded compound [{(ddp)Ga(Cl)}PbMe<jats:sub>3<\/jats:sub>] (<jats:bold>1<\/jats:bold>) composed of Ga\uf8ffPb<jats:sup>IV<\/jats:sup> bonds. In addition, the monomeric plumbylene\u2010type compound [{(ddp)Ga(OSO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>)}<jats:sub>2<\/jats:sub>Pb(thf)] (<jats:bold>2\u2009a<\/jats:bold>) with an unsupported Ga\u2010Pb<jats:sup>II<\/jats:sup>\u2010Ga linkage was obtained by the reaction of [Pb(OSO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>] with Ga(ddp) (2\u2005equiv). Compound <jats:bold>2\u2009a<\/jats:bold> falls under the rare example of a discrete plumbylene\u2010type compound supported by a nonclassical ligand. Interesting structural changes were observed when [Pb(OSO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]<jats:bold>\u22c5<\/jats:bold>2\u2009H<jats:sub>2<\/jats:sub>O was treated with Ga(ddp) in a 1:2 ratio to yield [{(ddp)Ga(\u03bc\u2010OSO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>)}<jats:sub>2<\/jats:sub>(OH<jats:sub>2<\/jats:sub>)Pb] (<jats:bold>2\u2009b<\/jats:bold>) at below \u221210\u2009\u00b0C. Compound <jats:bold>2\u2009b<\/jats:bold> consists of a bent Ga\u2010Pb\u2010Ga backbone with a bridging triflate group between the Ga\uf8ffPb bond and a weakly interacting water molecule at the gallium center. Similarly, the reaction of mercury thiolate Hg(SC<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>) with Ga(ddp) (2\u2005equiv) produced the bimetallic homoleptic compounds <jats:italic>anti\u2010<\/jats:italic>[{(ddp)Ga(SC<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)}<jats:sub>2<\/jats:sub>Hg] (<jats:bold>3\u2009a<\/jats:bold>) and <jats:italic>gauche<\/jats:italic>\u2010[{(ddp)Ga(SC<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)}<jats:sub>2<\/jats:sub>Hg] (<jats:bold>3\u2009b<\/jats:bold>), respectively, with a linear Ga\u2010Hg\u2010Ga linkage. Compounds <jats:bold>1<\/jats:bold>\u2013<jats:bold>3<\/jats:bold> were structurally characterized and these are the first examples of compounds comprised of Ga\uf8ffPb<jats:sup>II<\/jats:sup>, Ga\uf8ffPb<jats:sup>IV<\/jats:sup>, and Ga\uf8ffHg bonds.<\/jats:p>","DOI":"10.1002\/chem.200903330","type":"journal-article","created":{"date-parts":[[2010,4,13]],"date-time":"2010-04-13T14:36:21Z","timestamp":1271169381000},"page":"6041-6047","source":"Crossref","is-referenced-by-count":36,"title":["Group\u200513 Ligand Supported Heavy\u2010Metal Complexes: First Structural Evidence for Gallium\u2013Lead and Gallium\u2013Mercury 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