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The peak broadening in the <jats:sup>1<\/jats:sup>H\u2005spectrum of the copper complex indicates the paramagnetic behaviour of this compound. A square\u2010planar geometry around the nickel and copper complexes and distorted linear geometry around the mercury complex have been found. The latter geometry is attributed to the bulkiness of the methylferrocenyl and benzyl groups. The observed single quasi\u2010reversible cyclic voltammograms for complexes <jats:bold>2<\/jats:bold>, <jats:bold>8<\/jats:bold> and <jats:bold>9<\/jats:bold> indicate the stabilisation of a metal centre other than Fe in their characteristic oxidation state. These complexes have been used as a photosensitiser in dye\u2010sensitised solar cells.<\/jats:p>","DOI":"10.1002\/chem.200903367","type":"journal-article","created":{"date-parts":[[2010,2,18]],"date-time":"2010-02-18T14:43:29Z","timestamp":1266504209000},"page":"4307-4314","source":"Crossref","is-referenced-by-count":124,"title":["Synthesis, Structure and Light\u2010Harvesting Properties of Some New Transition\u2010Metal Dithiocarbamates Involving Ferrocene"],"prefix":"10.1002","volume":"16","author":[{"given":"Abhinav","family":"Kumar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ratna","family":"Chauhan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kieran\u2005C.","family":"Molloy","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gabriele","family":"Kociok\u2010K\u00f6hn","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lal","family":"Bahadur","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nanhai","family":"Singh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,4]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"Ferrocenes","author":"Togni A.","year":"1995"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619542"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951070105"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199500211"},{"key":"e_1_2_6_5_2","volume-title":"Metallocenes: An Introduction to Sandwich Complexes","author":"Long N. 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