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In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1)\u2005a tandem Meyer\u2013Schuster rearrangement\/reduction to access enantioenriched allylic alcohols and 2)\u2005the enantioselective reduction of imines.<\/jats:p>","DOI":"10.1002\/chem.201001164","type":"journal-article","created":{"date-parts":[[2010,7,7]],"date-time":"2010-07-07T14:59:39Z","timestamp":1278514779000},"page":"9555-9562","source":"Crossref","is-referenced-by-count":99,"title":["Enantioselective Reduction of Ketones and Imines Catalyzed by (CN\u2010Box)Re<sup>V<\/sup>\u2013Oxo Complexes"],"prefix":"10.1002","volume":"16","author":[{"given":"Kristine\u2005A.","family":"Nolin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard\u2005W.","family":"Ahn","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuke","family":"Kobayashi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joshua\u2005J.","family":"Kennedy\u2010Smith","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"F.\u2005Dean","family":"Toste","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,8,12]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.2174\/157017907780598907"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja029498q"},{"key":"e_1_2_6_3_2","unstructured":"\u00a0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-3055(07)55001-X"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.2174\/138527208785740238"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.2174\/157017909788921871"},{"key":"e_1_2_6_7_2","unstructured":"For examples of reduction of various functional groups with silanes catalyzed by rhenium\u2013oxo complexes. 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