{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T17:36:21Z","timestamp":1787506581082,"version":"build-2736575974"},"reference-count":94,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2010,10,11]],"date-time":"2010-10-11T00:00:00Z","timestamp":1286755200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2010,12,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The synthesis and structural characterization of novel, metal\u2010rich, highly coordinated compounds [Mo(M\u2032R)\n                    <jats:sub>12<\/jats:sub>\n                    ] and [M(M\u2032R)\n                    <jats:sub>8<\/jats:sub>\n                    ] (M: Pd, Pt, Mo; M\u2032: Zn, Cd; R: Me=CH\n                    <jats:sub>3<\/jats:sub>\n                    , Cp*=pentamethylcyclopentadienyl) are reported. Additionally, a description of the bonding situation of the new compounds by means of quantum\u2010chemical calculations is presented including the Hg analogues. Reaction of [Pt(GaCp*)\n                    <jats:sub>4<\/jats:sub>\n                    ] with CdMe\n                    <jats:sub>2<\/jats:sub>\n                    results in the formation of the unprecedented all\u2010Cd coordinated [Pt(CdMe)\n                    <jats:sub>4<\/jats:sub>\n                    (CdCp*)\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ). Similarly, the treatment of the all\u2010Zn coordinated [Pd(ZnMe)\n                    <jats:sub>4<\/jats:sub>\n                    (ZnCp*)\n                    <jats:sub>4<\/jats:sub>\n                    ] with CdMe\n                    <jats:sub>2<\/jats:sub>\n                    affords the novel Zn\/Cd mixed compound [Pd(CdMe)\n                    <jats:sub>4<\/jats:sub>\n                    (ZnCp*)\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>2<\/jats:bold>\n                    ). The related Zn\/Cd mixed compound [Mo(ZnCp*)\n                    <jats:sub>3<\/jats:sub>\n                    (CdMe)\n                    <jats:sub>9<\/jats:sub>\n                    ] (\n                    <jats:bold>3<\/jats:bold>\n                    ) is prepared by reaction of [Mo(ZnCp*)\n                    <jats:sub>4<\/jats:sub>\n                    (GaMe)\n                    <jats:sub>4<\/jats:sub>\n                    ] with an excess amount of CdMe\n                    <jats:sub>2<\/jats:sub>\n                    . All compounds were analyzed by\n                    <jats:sup>1<\/jats:sup>\n                    H and\n                    <jats:sup>13<\/jats:sup>\n                    C\u2005NMR spectroscopy, elemental analysis, and single\u2010crystal X\u2010ray diffraction. The bonding situation of these highly coordinated, metal\u2010rich molecules\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    were studied by quantum\u2010chemical calculations using density functional theory (DFT) at the BP86\/TZ2P+ level, atoms\u2010in\u2010molecules (AIM) analysis, and energy\u2010decomposition analysis (EDA), as well as the its natural orbitals for chemical valence variation (EDA\u2010NOCV) and including the hypothetically all\u2010Hg\u2010coordinated analogues. The results point out that the radial interactions M\u2013M\u2032 in the icosahedral compounds that have twelve ligands are best described as classical electron\u2010pair\u2010sharing covalent bonds, whereas the dodecahedral species, which have eight ligands, exhibit metal\u2013ligand donor\u2013acceptor bonds. The attractive interactions between the metal\u2013ligand fragments M\u2032R by means of M\u2032\u2013M\u2032 bonds are weaker but not insignificant. All complexes fulfill the 18\u2010electron rule. The analysis clarifies the electronic structures as being distinctly different from typical endohedral clusters M@(M\u2032\u2032R)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    that exhibit strong peripheral M\u2032\u2032\u2013M\u2032\u2032 interactions: The M\u2032\uf8ffM\u2032 bonds are not strong enough to yield stable (M\u2032R)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    cages.\n                  <\/jats:p>","DOI":"10.1002\/chem.201001650","type":"journal-article","created":{"date-parts":[[2010,10,11]],"date-time":"2010-10-11T13:49:09Z","timestamp":1286804949000},"page":"13372-13384","source":"Crossref","is-referenced-by-count":30,"title":["Molecular Alloys: Experimental and Theoretical Investigations on the Substitution of Zinc by Cadmium and Mercury in the Homologous Series [Mo(M\u2032R)\n                    <sub>12<\/sub>\n                    ] and [M(M\u2032R)\n                    <sub>8<\/sub>\n                    ] (M=Pd, Pt; M\u2032=Zn, Cd, Hg)"],"prefix":"10.1002","volume":"16","author":[{"given":"Timo","family":"Bollermann","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas","family":"Cadenbach","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Gemel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Moritz","family":"von\u2005Hopffgarten","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gernot","family":"Frenking","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roland 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