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The treatment of <jats:bold>1<\/jats:bold> with germanium chloride ([LGeCl]), tin chloride ([LSnCl]; L=CH(CMe2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>N)<jats:sub>2<\/jats:sub>), bismuth amide ([1,8\u2010C<jats:sub>10<\/jats:sub>H<jats:sub>6<\/jats:sub>(NSiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>BiNMe<jats:sub>2<\/jats:sub>]), and dimethyl zinc (ZnMe<jats:sub>2<\/jats:sub>) gave the desired compounds with different functional groups on the aluminum center. All compounds have been thoroughly characterized by multinuclear NMR spectroscopy, EI mass spectrometry, X\u2010ray crystallography (<jats:bold>2<\/jats:bold>, <jats:bold>3<\/jats:bold>, and <jats:bold>5<\/jats:bold>), and elemental analysis.<\/jats:p>","DOI":"10.1002\/chem.201001809","type":"journal-article","created":{"date-parts":[[2010,11,19]],"date-time":"2010-11-19T10:52:47Z","timestamp":1290163967000},"page":"890-894","source":"Crossref","is-referenced-by-count":22,"title":["A New Entry into Aluminum Chemistry: [L<sup>1<\/sup>AlMe]\u22c5THF, a Versatile Building Block for Bimetallic and Polymetallic Complexes"],"prefix":"10.1002","volume":"17","author":[{"given":"Sankaranarayana Pillai","family":"Sarish","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bijan","family":"Nekoueishahraki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anukul","family":"Jana","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Herbert W.","family":"Roesky","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thomas","family":"Schulz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dietmar","family":"Stalke","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,11,19]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic000807s"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.96.027216"},{"key":"e_1_2_6_4_2","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja043585w"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050521s"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic060538r"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om070235k"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/B614558B"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar9001729"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b822148k"},{"key":"e_1_2_6_13_2","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(99)00137-0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0203328"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351055"},{"key":"e_1_2_6_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351055"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400159"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0600230"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600237"},{"key":"e_1_2_6_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600237"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/om049339a"},{"key":"e_1_2_6_21_2","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00001a018"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990201)111:3<365::AID-ANGE365>3.0.CO;2-I"},{"key":"e_1_2_6_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990201)38:3<354::AID-ANIE354>3.0.CO;2-P"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000871h"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic8015639"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901215"},{"key":"e_1_2_6_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901215"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic701896r"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/om970886o"},{"key":"e_1_2_6_29_2","unstructured":"\u00a0"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889893002018"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/a827171z"},{"key":"e_1_2_6_32_2","unstructured":"SAINT\u2010NT Bruker AXS Inc. 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