{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,24]],"date-time":"2026-01-24T14:59:53Z","timestamp":1769266793460,"version":"3.49.0"},"reference-count":143,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2011,3,14]],"date-time":"2011-03-14T00:00:00Z","timestamp":1300060800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2011,4,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The nitroprusside ion [Fe(CN)<jats:sub>5<\/jats:sub>NO]<jats:sup>2\u2212<\/jats:sup> (NP) reacts with excess HS<jats:sup>\u2212<\/jats:sup> in the pH range 8.5\u201312.5, in anaerobic medium (\u201cGmelin\u201d reaction). The progress of the addition process of HS<jats:sup>\u2212<\/jats:sup> into the bound NO<jats:sup>+<\/jats:sup> ligand was monitored by stopped\u2010flow UV\/Vis\/EPR and FTIR spectroscopy, mass spectrometry, and chemical analysis. Theoretical calculations were employed for the characterization of the initial adducts and reaction intermediates. The shapes of the absorbance\u2013time curves at 535\u2013575\u2005nm depend on the pH and concentration ratio of the reactants, <jats:italic>R<\/jats:italic>=[HS<jats:sup>\u2212<\/jats:sup>]\/[NP]. The initial adduct [Fe(CN)<jats:sub>5<\/jats:sub>N(O)SH]<jats:sup>3\u2212<\/jats:sup> (<jats:bold>AH<\/jats:bold>, <jats:italic>\u03bb<\/jats:italic><jats:sub>max<\/jats:sub>\u2248570\u2005nm) forms in the course of a reversible process, with <jats:italic>k<\/jats:italic><jats:sub>ad<\/jats:sub>=190\u00b120\u2009<jats:sc>M<\/jats:sc><jats:sup>\u22121<\/jats:sup>\u2009s<jats:sup>\u22121<\/jats:sup>, <jats:italic>k<\/jats:italic><jats:sub>\u2010ad<\/jats:sub>=0.3\u00b10.05\u2005s<jats:sup>\u22121<\/jats:sup>. Deprotonation of <jats:bold>AH<\/jats:bold> (p<jats:italic>K<\/jats:italic><jats:sub>a<\/jats:sub>=10.5\u00b10.1, at 25.0\u2009\u00b0C, <jats:italic>I<\/jats:italic>=1\u2009<jats:sc>M<\/jats:sc>), leads to [Fe(CN)<jats:sub>5<\/jats:sub>N(O)S]<jats:sup>4\u2212<\/jats:sup> (<jats:bold>A<\/jats:bold>, <jats:italic>\u03bb<\/jats:italic><jats:sub>max<\/jats:sub>=535\u2005nm, <jats:italic>\u03b5<\/jats:italic>=6000\u00b1300\u2009<jats:sc>M<\/jats:sc><jats:sup>\u22121<\/jats:sup>\u2009cm<jats:sup>\u22121<\/jats:sup>). [Fe(CN)<jats:sub>5<\/jats:sub>NO]<jats:bold><jats:sup>.<\/jats:sup><\/jats:bold><jats:sup>3\u2212<\/jats:sup> and HS<jats:sub>2<\/jats:sub><jats:bold><jats:sup>.<\/jats:sup><\/jats:bold><jats:sup>2\u2212<\/jats:sup> radicals form through the spontaneous decomposition of <jats:bold>AH<\/jats:bold> and <jats:bold>A<\/jats:bold>. The minor formation of the [Fe(CN)<jats:sub>5<\/jats:sub>NO]<jats:sup>3\u2212<\/jats:sup> ion equilibrates with [Fe(CN)<jats:sub>4<\/jats:sub>NO]<jats:sup>2\u2212<\/jats:sup> through cyanide labilization, and generates the \u201c<jats:italic>g<\/jats:italic>=2.03\u201d iron\u2013dinitrosyl, [Fe(NO)<jats:sub>2<\/jats:sub>(SH)<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>, which is labile toward NO release. Alternative nucleophilic attack of HS<jats:sup>\u2212<\/jats:sup> on <jats:bold>AH<\/jats:bold> and <jats:bold>A<\/jats:bold> generates the reactive intermediates [Fe(CN)<jats:sub>5<\/jats:sub>N(OH)(SH)<jats:sub>2<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup> and [Fe(CN)<jats:sub>5<\/jats:sub>N(OH)(S)(SH)]<jats:sup>4\u2212<\/jats:sup>, respectively, which decompose through multielectronic nitrosyl reductions, leading to NH<jats:sub>3<\/jats:sub> and hydrogen disulfide, HS<jats:sub>2<\/jats:sub><jats:sup>\u2212<\/jats:sup>. N<jats:sub>2<\/jats:sub>O is also produced at pH\u226511. Biological relevance relates to the role of NO, NO<jats:sup>\u2212<\/jats:sup>, and other bound intermediates, eventually able to be released to the medium and rapidly trapped by substrates. Structure and reactivity comparisons of the new nitrososulfide ligands with free and bound nitrosothiolates are provided.<\/jats:p>","DOI":"10.1002\/chem.201002322","type":"journal-article","created":{"date-parts":[[2011,3,14]],"date-time":"2011-03-14T09:38:36Z","timestamp":1300095516000},"page":"4145-4156","source":"Crossref","is-referenced-by-count":42,"title":["Addition and Redox Reactivity of Hydrogen Sulfides (H<sub>2<\/sub>S\/HS<sup>\u2212<\/sup>) with Nitroprusside: New Chemistry of Nitrososulfide Ligands"],"prefix":"10.1002","volume":"17","author":[{"given":"Sandra L.","family":"Quiroga","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alejandra E.","family":"Almaraz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Valent\u00edn T.","family":"Amorebieta","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Laura L.","family":"Perissinotti","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9 A.","family":"Olabe","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2011,3,14]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"Nitric Oxide: Biology and Pathobiology","year":"2000"},{"key":"e_1_2_6_3_2","volume-title":"Methods in Nitric Oxide Research","year":"1996"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020623q"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/bies.20005"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1124\/pr.57.4.3"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1152\/physrev.00011.2005"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1523\/JNEUROSCI.16-03-01066.1996"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1152\/ajpregu.90566.2008"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1242\/jeb.02480"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1006\/bbrc.1997.6878"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tips.2007.11.003"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1162667"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1046\/j.1471-4159.2002.01097.x"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/0005-2728(81)90170-5"},{"key":"e_1_2_6_18_2","unstructured":"\u00a0"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2004.10.012"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1152\/physrev.2001.81.2.569"},{"key":"e_1_2_6_21_2","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470166284.ch3"},{"key":"e_1_2_6_23_2","first-page":"269","author":"Deutsch E.","year":"1983","journal-title":"Adv. Inorg. Bioinorg. Mech."},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic901853p"},{"key":"e_1_2_6_25_2","unstructured":"\u00a0"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18500740306"},{"key":"e_1_2_6_27_2","first-page":"1315","volume-title":"The Chemical Elements and Their Compounds, Vol.\u2005II","author":"Sidgwick N. V.","year":"1950"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50040a026"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac00025a008"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)81208-5"},{"key":"e_1_2_6_31_2","volume-title":"Reactions of Coordinated Ligands, Vol.\u20052","author":"Bottomley F.","year":"1989"},{"key":"e_1_2_6_32_2","unstructured":"\u00a0"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/b803153c"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.04.012"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0898-8838(03)55002-4"},{"key":"e_1_2_6_36_2","unstructured":"\u00a0"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.03.021"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1367-5931(02)00383-6"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.3184\/007967401103165181"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar9800439"},{"key":"e_1_2_6_41_2","unstructured":"\u00a0"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1139\/v75-325"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100304a014"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-006-0164-7"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/qua.20876"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)02011-7"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr000076d"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.96.26.14753"},{"key":"e_1_2_6_49_2","unstructured":"Niehs spin trap database http:\/\/tools.niesh.nih.gov\/stdb\/index.cfm."},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja025995v"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046724i"},{"key":"e_1_2_6_52_2","first-page":"126","volume-title":"Methods of Seawater Analysis","author":"Koroleff F.","year":"1976"},{"key":"e_1_2_6_53_2","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria J.\u2005R. Cheeseman V.\u2005G. Zakrzewski J.\u2005A. Montgomery\u2005Jr. R. Stratmann J. Burant S. Dapprich J.\u2005M. Millam A.\u2005D. Daniels K.\u2005N. Kudin M.\u2005C. Strain O. Farkas J. Tomasi V. Barone M. Cossi R. Cammi B. Mennucci C. Pomelli C. Adamo S. Clifford J. Ochterski G.\u2005A. Petersson P.\u2005Y. Ayala Q. Cui K. Morokuma D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J. Cioslowski J.\u2005V. Ortiz A.\u2005G. Baboul B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R. Gomperts R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010Laham C.\u2005Y. Peng A. Nanayakkara C. Gonzalez M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong J.\u2005L. Andres C. Gonzalez M. Head\u2010Gordon E.\u2005S. Replogle J.\u2005A. Pople Gaussian 98 Rev. A7 Gaussian Inc. Pittsburgh PA1998."},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00349-1"},{"key":"e_1_2_6_56_2","unstructured":"\u00a0"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.540160911"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.472065"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp962071j"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/1096-987X(200012)21:16<1419::AID-JCC1>3.0.CO;2-C"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00051a040"},{"key":"e_1_2_6_62_2","unstructured":"\u00a0"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00440-X"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.477483"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.2173258"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100180a030"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00522a025"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.477096"},{"key":"e_1_2_6_68_3","volume-title":"Statistical Mechanics","author":"McQuarrie D. A.","year":"1970"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp055336f"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp982638r"},{"key":"e_1_2_6_71_2","unstructured":"\u00a0"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.449486"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00088a005"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"e_1_2_6_75_2","unstructured":"Persistence of Vision Pty. Ltd. 2004 Persistence of Vision Raytracer (Version 3.6) [computer software]; retrieved from http:\/\/www.povray.org\/download\/."},{"key":"e_1_2_6_76_2","unstructured":"\u00a0"},{"key":"e_1_2_6_77_2","volume-title":"CRC Handbook of Chemistry and Physics","year":"2003"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-9140(97)00045-3"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00158a027"},{"key":"e_1_2_6_80_2","unstructured":"The first spectra of Figures\u20055 and 6 show a similar dependence on the pH for the intensity and maximum wavelength at constant R. Now the maxima are attained at 570 and 535\u2005nm at pH\u20059.5 and 11.5 respectively."},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527600825"},{"key":"e_1_2_6_82_2","unstructured":"The optimal conditions for observing the dependence ofDwith the pH for [H+]\u226bK2 isR=10 for whichD\u2248k\u22121. For the highest studied value ofR=100 the relative contribution ofk\u20101toDis nearly 30\u2009%. This fact is in agreement with the reported pH independence when the reaction was studied atR\u2265100. Thus the line displayed in Figure\u20053 was calculated by fitting the data forR=10 and 30."},{"key":"e_1_2_6_83_2","unstructured":"\u00a0"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01150847"},{"key":"e_1_2_6_85_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00664238"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp953179m"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic960377z"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic961426a"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic960534u"},{"key":"e_1_2_6_90_2","unstructured":"\u00a0"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0565976"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic7024999"},{"key":"e_1_2_6_93_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9901314"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic025653q"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00390a020"},{"key":"e_1_2_6_96_2","volume-title":"Inorganic Electronic Spectroscopy","author":"Lever A. B. P.","year":"1985"},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00168a068"},{"key":"e_1_2_6_98_2","unstructured":"\u00a0"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9810000435"},{"key":"e_1_2_6_100_2","first-page":"893","volume":"21","author":"Szacilowski K.","year":"1997","journal-title":"New J. Chem."},{"key":"e_1_2_6_101_2","doi-asserted-by":"publisher","DOI":"10.1039\/B204719P"},{"key":"e_1_2_6_102_2","unstructured":"\u00a0"},{"key":"e_1_2_6_103_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi973153g"},{"key":"e_1_2_6_104_2","doi-asserted-by":"publisher","DOI":"10.1139\/v98-062"},{"key":"e_1_2_6_105_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.93.25.14428"},{"key":"e_1_2_6_106_2","doi-asserted-by":"publisher","DOI":"10.1006\/abbi.1995.1231"},{"key":"e_1_2_6_107_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50175a008"},{"key":"e_1_2_6_108_2","unstructured":"The assignment of the reaction in Equation\u2005(4) as a spontaneous decomposition of the adduct is supported by our complementary experiments in excess of NP in which a very similar rate of [Fe(CN)5NO]3\u2212production has been observed."},{"key":"e_1_2_6_109_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp9907544"},{"key":"e_1_2_6_110_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja044056v"},{"key":"e_1_2_6_111_2","unstructured":"Formation of dominant NH3and other reduction products (N2O NO NH2OH) in the reactions of free nitrosothiolates with an excess of thiolate allowed proposing diverse structures for the intermediates and their further reactivity modes.[51]We rely on our calculations of the atomic charges forAH Aand a related nitrosothiolate (see Table\u2005SI6 in the Supporting Information) revealing that the most positively charged N atom in the Fe\uf8ffNOS(H) moieties should be the expected site for the nucleophilic attack of HS\u2212. The attack on the S atom of the NOSR group has also been considered for free and protonated nitrosothiolates.[50 \u200951a]"},{"key":"e_1_2_6_112_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.08.010"},{"key":"e_1_2_6_113_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200806229"},{"key":"e_1_2_6_114_2","doi-asserted-by":"publisher","DOI":"10.1135\/cccc19742141"},{"key":"e_1_2_6_115_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic902423v"},{"key":"e_1_2_6_116_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50126a063"},{"key":"e_1_2_6_117_2","unstructured":"\u00a0"},{"key":"e_1_2_6_118_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00279a036"},{"key":"e_1_2_6_119_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00227a032"},{"key":"e_1_2_6_120_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00258a022"},{"key":"e_1_2_6_121_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00004a008"},{"key":"e_1_2_6_122_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00041a022"},{"key":"e_1_2_6_123_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0006627"},{"key":"e_1_2_6_124_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00210a047"},{"key":"e_1_2_6_125_2","unstructured":"\u00a0"},{"key":"e_1_2_6_126_2","doi-asserted-by":"publisher","DOI":"10.1016\/0020-1650(74)80218-7"},{"key":"e_1_2_6_127_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1727437"},{"key":"e_1_2_6_128_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)81731-4"},{"key":"e_1_2_6_129_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010452s"},{"key":"e_1_2_6_130_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja982491h"},{"key":"e_1_2_6_131_2","doi-asserted-by":"publisher","DOI":"10.1006\/niox.1998.0180"},{"key":"e_1_2_6_132_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)87029-1"},{"key":"e_1_2_6_133_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic050070c"},{"key":"e_1_2_6_134_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja017061x"},{"key":"e_1_2_6_135_2","unstructured":"\u00a0"},{"key":"e_1_2_6_136_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50123a013"},{"key":"e_1_2_6_137_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50127a026"},{"key":"e_1_2_6_138_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00170a022"},{"key":"e_1_2_6_139_2","doi-asserted-by":"publisher","DOI":"10.1039\/a604148e"},{"key":"e_1_2_6_140_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic048156d"},{"key":"e_1_2_6_141_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja066900i"},{"key":"e_1_2_6_142_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00154a007"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201002322","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201002322","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T11:54:11Z","timestamp":1760270051000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201002322"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,3,14]]},"references-count":143,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2011,4,4]]}},"alternative-id":["10.1002\/chem.201002322"],"URL":"https:\/\/doi.org\/10.1002\/chem.201002322","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,3,14]]}}}