{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T20:25:53Z","timestamp":1791318353226,"version":"4.3.1"},"reference-count":49,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2011,2,25]],"date-time":"2011-02-25T00:00:00Z","timestamp":1298592000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2011,3,21]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Molybdenum and chromium pentacarbonyldiphenylphosphinocarbodithioate complexes have been prepared in a one\u2010pot reaction from the corresponding metallocarbonyldiphenylphosphine. The complexes have been characterised by IR, <jats:sup>1<\/jats:sup>H, <jats:sup>31<\/jats:sup>P and <jats:sup>13<\/jats:sup>C\u2005NMR spectroscopies and by mass spectrometry. The solid\u2010state structures of [Cr(CO)<jats:sub>5<\/jats:sub>{PPh<jats:sub>2<\/jats:sub>CS<jats:sub>2<\/jats:sub>CH(Ph)CH<jats:sub>3<\/jats:sub>}] (<jats:bold>1<\/jats:bold>) and [Mo(CO)<jats:sub>5<\/jats:sub>{PPh<jats:sub>2<\/jats:sub>CS<jats:sub>2<\/jats:sub>CH(Ph)CH<jats:sub>3<\/jats:sub>}] (<jats:bold>2<\/jats:bold>) are reported. Compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> are isostructural and crystallise in the triclinic <jats:italic>P<\/jats:italic><jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/> space group. These new organometallic compounds are highly efficient reversible chain\u2010transfer agents for reversible addition\u2013fragmentation chain\u2010transfer (RAFT) polymerisation of styrene (St) and <jats:italic>n<\/jats:italic>\u2010butyl acrylate (<jats:italic>n<\/jats:italic>BA), with controlled number\u2010average molar mass values and narrow dispersities (&lt;1.2). The controlled character of the polymerisation was further exemplified by the synthesis of St and <jats:italic>n<\/jats:italic>BA diblock copolymers.<\/jats:p>","DOI":"10.1002\/chem.201002342","type":"journal-article","created":{"date-parts":[[2011,2,26]],"date-time":"2011-02-26T10:46:54Z","timestamp":1298717214000},"page":"3718-3725","source":"Crossref","is-referenced-by-count":16,"title":["Chromium and Molybdenum Pentacarbonyl Complexes of Phosphinocarbodithioates: Synthesis, Molecular Structure and Behaviour in RAFT Polymerisation"],"prefix":"10.1002","volume":"17","author":[{"given":"Roland","family":"Geagea","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sonia","family":"Ladeira","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"St\u00e9phane","family":"Mazi\u00e8res","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mathias","family":"Destarac","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,2,25]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1351\/PAC-REP-08-04-03"},{"key":"e_1_2_6_3_2","volume-title":"Controlled\/Living Radical Polymerization: Progress in ATRP","year":"2009"},{"key":"e_1_2_6_4_2","unstructured":"Controlled\/Living Radical Polymerization: Progress in RAFT DT NMP and OMRP(Ed.: K. 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