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The discussion is focused on the relationship between them, including the evolution from the Au\u22c5\u22c5\u22c5Au aurophilic interaction in Au<jats:sup>I<\/jats:sup> complexes to the direct Au\uf8ffAu bond in clusters, and the structural transformation from the fcc structure in nanocrystals to non\u2010fcc structures in nanoclusters. Thiolate\u2010protected Au<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>(SR)<jats:sub><jats:italic>m<\/jats:italic><\/jats:sub> nanoclusters are used as a paradigm system. Research on such nanoclusters has achieved considerable advances in recent years and is expected to flourish in the near future, which will bring about exciting progress in both fundamental scientific research and technological applications of nanoclusters of gold and other metals.<\/jats:p>","DOI":"10.1002\/chem.201002390","type":"journal-article","created":{"date-parts":[[2011,5,17]],"date-time":"2011-05-17T07:01:52Z","timestamp":1305615712000},"page":"6584-6593","source":"Crossref","is-referenced-by-count":148,"title":["Quantum\u2010Sized Gold Nanoclusters: Bridging the Gap between Organometallics and 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