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The use of sulfinate salts as nucleophiles in substitutions is frequently accompanied by side reactions such as \u03c0\u2010bond migration, \u03b2\u2010elimination, and so on. Herein we present a preparatively simple way to synthesize a variety of different aryl or alkyl allyl sulfones starting from readily accessible allylic carbonates. By employing aryl or alkyl \u03b1\u2010sulfonyl succinimides as sulfinate synthons, mild and regioselective <jats:italic>ipso<\/jats:italic> substitution of diverse allylic carbonates was realized.<\/jats:p>","DOI":"10.1002\/chem.201101047","type":"journal-article","created":{"date-parts":[[2011,8,4]],"date-time":"2011-08-04T12:34:21Z","timestamp":1312461261000},"page":"10417-10430","source":"Crossref","is-referenced-by-count":64,"title":["\u03b1\u2010Sulfonyl Succinimides: Versatile Sulfinate Donors in Fe\u2010Catalyzed, Salt\u2010Free, Neutral Allylic Substitution"],"prefix":"10.1002","volume":"17","author":[{"given":"Markus","family":"Jegelka","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bernd","family":"Plietker","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,8,4]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"Sulfones in Organic Synthesis","year":"1993"},{"key":"e_1_2_6_3_2","volume-title":"The Chemistry Functional Groups: Sulfones and Sulfoxides","year":"1988"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b911852g"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)91577-7"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)84463-0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981016)110:20<3056::AID-ANGE3056>3.0.CO;2-J"},{"key":"e_1_2_6_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981102)37:20<2864::AID-ANIE2864>3.0.CO;2-W"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)87301-3"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)92030-6"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol051049i"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1987.1939"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2004.04.162"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39940002261"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol060608y"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(85)88099-2"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2005-921932"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol017142y"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200501606"},{"key":"e_1_2_6_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200501606"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00291a001"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00538a079"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(83)85087-6"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(86)80547-2"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)87370-0"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00335a075"},{"key":"e_1_2_6_25_2","first-page":"985","author":"Martel J.","year":"1967","journal-title":"Bull. 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