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The polymeric compounds have been characterised by single\u2010crystal X\u2010ray diffraction analyses and, for selected examples, by magic angle spinning (MAS) NMR spectroscopy. The solid\u2010state structures demonstrate the versatile coordination modes of the <jats:italic>cyclo\u2010<\/jats:italic>P<jats:sub>5<\/jats:sub> ligand of <jats:bold>1<\/jats:bold>, extending from two to five coordinating phosphorus atoms in either \u03c3 or \u03c3\u2010and\u2010\u03c0 fashion. In compounds <jats:bold>2\u2009a<\/jats:bold>, <jats:bold>2\u2032c<\/jats:bold> and <jats:bold>3<\/jats:bold>, two phosphorus atoms of <jats:bold>1<\/jats:bold> coordinate to copper atoms in a 1,2 coordination mode (<jats:bold>2\u2009a<\/jats:bold>, <jats:bold>2\u2032c<\/jats:bold>) and an unprecedented 1,3 coordination mode (<jats:bold>3<\/jats:bold>) to form one\u2010dimensional polymers. Compounds <jats:bold>4\u2009a<\/jats:bold>\u2013<jats:bold>c<\/jats:bold>, <jats:bold>4\u2032b<\/jats:bold>, <jats:bold>4\u2032c<\/jats:bold> and <jats:bold>5<\/jats:bold> represent two\u2010dimensional coordination polymers. In compounds <jats:bold>4<\/jats:bold>, three phosphorus atoms coordinate to copper atoms in a 1,2,4 coordination mode, whereas in <jats:bold>5<\/jats:bold> the <jats:italic>cyclo\u2010<\/jats:italic>P<jats:sub>5<\/jats:sub> ligand binds in an unprecedented 1,2,3,4 coordination mode. The crystal structures of <jats:bold>6\u2009a<\/jats:bold>,<jats:bold>b<\/jats:bold> display a tilted tube, in which all P atoms of the <jats:italic>cyclo\u2010<\/jats:italic>P<jats:sub>5<\/jats:sub> ligand are coordinated to copper atoms in \u03c3\u2010 and \u03c0\u2010bonding modes.<\/jats:p>","DOI":"10.1002\/chem.201102107","type":"journal-article","created":{"date-parts":[[2011,12,24]],"date-time":"2011-12-24T18:24:16Z","timestamp":1324751056000},"page":"1168-1179","source":"Crossref","is-referenced-by-count":63,"title":["Coordination Polymers Based on [Cp*Fe(\u03b7<sup>5<\/sup>\u2010P<sub>5<\/sub>)]: Solid\u2010State Structure and MAS NMR Studies"],"prefix":"10.1002","volume":"18","author":[{"given":"Fabian","family":"Dielmann","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Schindler","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sabine","family":"Scheuermayer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junfeng","family":"Bai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roger","family":"Merkle","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Zabel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander V.","family":"Virovets","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eugenia V.","family":"Peresypkina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gunther","family":"Brunklaus","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hellmut","family":"Eckert","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,12,23]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"For recent review articles see:"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805340"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805340"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar900077c"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja803783c"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.10.010"},{"key":"e_1_2_6_6_2","first-page":"4169","author":"Sarkar K. 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