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Based on the protection reaction between ethanethiol and aldehyde, the corresponding dithioacetals (compounds\n                    <jats:bold>S1<\/jats:bold>\n                    ,\n                    <jats:bold>S2<\/jats:bold>\n                    , and\n                    <jats:bold>S3<\/jats:bold>\n                    ) were prepared to serve as novel colorimetric and fluorescent chemosensors for Hg\n                    <jats:sup>2+<\/jats:sup>\n                    ions. Also, compound\n                    <jats:bold>S1<\/jats:bold>\n                    was further utilized to construct the chemical\u2010reaction\u2010based conjugated polymer probe (\n                    <jats:bold>PS1<\/jats:bold>\n                    ) towards Hg\n                    <jats:sup>2+<\/jats:sup>\n                    ions. In the presence of as little as 10\u2005n\n                    <jats:sc>M<\/jats:sc>\n                    Hg\n                    <jats:sup>2+<\/jats:sup>\n                    , compound\n                    <jats:bold>PS1<\/jats:bold>\n                    displayed an apparent change in the fluorescent intensity. The sensing processes were revealed to be mediated by ICT, as confirmed by time\u2010dependent DFT calculations. Furthermore, compound\n                    <jats:bold>S1<\/jats:bold>\n                    was successfully applied to microscopic imaging for the detection of Hg\n                    <jats:sup>2+<\/jats:sup>\n                    in HeLa cells with ratiometric fluorescent methods.\n                  <\/jats:p>","DOI":"10.1002\/chem.201102376","type":"journal-article","created":{"date-parts":[[2012,1,6]],"date-time":"2012-01-06T06:07:57Z","timestamp":1325830077000},"page":"1691-1699","source":"Crossref","is-referenced-by-count":91,"title":["Fluorescent and Colorimetric Probes for Mercury(II): Tunable Structures of Electron Donor and \u03c0\u2010Conjugated 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