{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T18:26:14Z","timestamp":1771266374079,"version":"3.50.1"},"reference-count":101,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2012,1,13]],"date-time":"2012-01-13T00:00:00Z","timestamp":1326412800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2012,2,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The first structural characterization of the text\u2010book tetraammineberyllium(II) cation [Be(NH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sup>2+<\/jats:sup>, obtained in the compounds [Be(NH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub><jats:bold>\u22c5<\/jats:bold>17NH<jats:sub>3<\/jats:sub> and [Be(NH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]Cl<jats:sub>2<\/jats:sub>, is reported. Through NMR spectroscopic and quantum chemical studies, its hydrolysis products in liquid ammonia were identified. These are the dinuclear [Be<jats:sub>2<\/jats:sub>(\u03bc\u2010OH)(NH<jats:sub>3<\/jats:sub>)<jats:sub>6<\/jats:sub>]<jats:sup>3+<\/jats:sup> and the cyclic [Be<jats:sub>2<\/jats:sub>(\u03bc\u2010OH)<jats:sub>2<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sup>2+<\/jats:sup> and [Be<jats:sub>3<\/jats:sub>(\u03bc\u2010OH)<jats:sub>3<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)<jats:sub>6<\/jats:sub>]<jats:sup>3+<\/jats:sup> cations. The latter species was isolated as the compound [Be<jats:sub>3<\/jats:sub>(\u03bc\u2010OH)<jats:sub>3<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)<jats:sub>6<\/jats:sub>]Cl<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>7NH<jats:sub>3<\/jats:sub>. NMR analysis of solutions of BeF<jats:sub>2<\/jats:sub> in liquid ammonia showed that the [BeF<jats:sub>2<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] molecule was the only dissolved species. It acts as a strong fluoride\u2010ion acceptor and forms the [BeF<jats:sub>3<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)]<jats:sup>\u2212<\/jats:sup> anion in the compound [N<jats:sub>2<\/jats:sub>H<jats:sub>7<\/jats:sub>][BeF<jats:sub>3<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)]. The compounds presented herein were characterized by single\u2010crystal X\u2010ray structure analysis, <jats:sup>9<\/jats:sup>Be, <jats:sup>17<\/jats:sup>O, and <jats:sup>19<\/jats:sup>F\u2005NMR, IR, and Raman spectroscopy, deuteration studies, and quantum chemical calculations. The extension of beryllium chemistry to the ammine system shows similarities but also decisive differences to the aquo system.<\/jats:p>","DOI":"10.1002\/chem.201103012","type":"journal-article","created":{"date-parts":[[2012,1,13]],"date-time":"2012-01-13T13:40:38Z","timestamp":1326462038000},"page":"2131-2142","source":"Crossref","is-referenced-by-count":59,"title":["Reactions of Beryllium Halides in Liquid Ammonia: The Tetraammineberyllium Cation [Be(NH<sub>3<\/sub>)<sub>4<\/sub>]<sup>2+<\/sup>, its Hydrolysis Products, and the Action of Be<sup>2+<\/sup> as a Fluoride\u2010Ion Acceptor"],"prefix":"10.1002","volume":"18","author":[{"given":"Florian","family":"Kraus","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sebastian A.","family":"Baer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Magnus R.","family":"Buchner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Antti J.","family":"Karttunen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2012,1,13]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800163"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200500438"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.4049\/jimmunol.175.10.7029"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1289\/ehp.0800455"},{"key":"e_1_2_6_5_2","first-page":"7","volume":"12","author":"Newman L. S.","year":"1995","journal-title":"Sarcoidosis"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.8105536"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/b718746g"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1093\/annhyg\/meq071"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1093\/annhyg\/meq073"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0300-483X(01)00410-3"},{"key":"e_1_2_6_11_2","doi-asserted-by":"crossref","first-page":"1647","DOI":"10.4049\/jimmunol.163.3.1647","volume":"163","author":"Wang Z.","year":"1999","journal-title":"J. Immunol."},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1515\/9783110177701.1"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja974049p"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00406-9"},{"key":"e_1_2_6_15_2","doi-asserted-by":"crossref","first-page":"1294","DOI":"10.1515\/znb-1998-1110","volume":"53","author":"Schmidt M.","year":"1998","journal-title":"Z. Naturforsch."},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic961410k"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic980481b"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.10-0985"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-2003-0127"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00015a032"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00074a050"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00061a031"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00063a034"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800145"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200700497"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.200890114"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800256"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.200590085"},{"key":"e_1_2_6_29_2","first-page":"523","volume-title":"Advances in Inorganic Chemistry and Radiochemistry","author":"Puchta R.","year":"2009"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200801360"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1080\/00958970108022906"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(94)80006-5"},{"key":"e_1_2_6_33_2","first-page":"1","volume-title":"The Chemistry of Beryllium","author":"Everest D. A.","year":"1964"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic970969x"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200700061"},{"key":"e_1_2_6_36_2","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1524\/zkri.1932.82.1.297","volume":"82","author":"Beevers C. A.","year":"1932","journal-title":"Z. Kristallogr."},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740869002159"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1976.144.1-6.314"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1996.211.3.170"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740869002160"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2004.06.033"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00843e"},{"key":"e_1_2_6_43_2","first-page":"1","volume-title":"Chemie in nichtw\u00e4\u00dfrigen ionisierenden L\u00f6sungsmitteln \u2010 Chemie in wasserfreiem fl\u00fcssigem Ammoniak","author":"Jander J.","year":"1966"},{"key":"e_1_2_6_44_2","first-page":"1","volume-title":"Topics in Inorganic and General Chemistry, Monograph 17: Inorganic Chemistry in liquid Ammonia","author":"Nicholls D.","year":"1979"},{"key":"e_1_2_6_45_2","first-page":"457","volume":"16","author":"Lebeau M. P.","year":"1899","journal-title":"Ann. Chim. Phys."},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19130800108"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01390a006"},{"key":"e_1_2_6_48_2","first-page":"469","volume":"10","author":"Grigor\u2032ev A. I.","year":"1969","journal-title":"Zhurnal Strukturnoi Khimii"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00720a011"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80404-X"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19251480119"},{"key":"e_1_2_6_52_2","first-page":"820","volume":"20","author":"Franklin E. C.","year":"1898","journal-title":"American Chemical Journal"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19271660131"},{"key":"e_1_2_6_54_2","first-page":"319","volume":"12","author":"Grigor\u2032ev A. I.","year":"1967","journal-title":"Russ. J. Inorg. Chem."},{"key":"e_1_2_6_55_2","doi-asserted-by":"crossref","first-page":"257","DOI":"10.1515\/znb-2009-0301","volume":"64","author":"Kraus F.","year":"2009","journal-title":"Z. Naturforsch."},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200900481"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000026"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000100"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981102)110:21<3204::AID-ANGE3204>3.0.CO;2-1"},{"key":"e_1_2_6_59_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981116)37:21<3007::AID-ANIE3007>3.0.CO;2-R"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981102)110:21<3204::AID-ANGE3204>3.0.CO;2-1"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2364(81)90191-8"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046712x"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2860(95)08850-U"},{"key":"e_1_2_6_64_2","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto K.","year":"1986"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19291800134"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19311970110"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19372310303"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1524\/zpch.1959.20.5_6.299"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50050a033"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01602a012"},{"key":"e_1_2_6_71_2","first-page":"1687","author":"Herlem M.","year":"1967","journal-title":"Bull. Soc. Chim. Fr."},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1080\/00032716908051269"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9870002431"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000250"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1992.1461"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740874002998"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00097a028"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1006\/jmre.1998.1565"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00659871"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1080\/00268970802018367"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1016\/0079-6565(88)80002-5"},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0016-7037(00)00395-1"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0016-7037(01)00816-X"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800980"},{"key":"e_1_2_6_85_2","unstructured":"Pfisterer K. Doktorarbeit Universit\u00e4t Regensburg 2002."},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881001118"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1992.200.3-4.225"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1993.203.Part-2.199"},{"key":"e_1_2_6_89_2","doi-asserted-by":"crossref","first-page":"1177","DOI":"10.1515\/znb-2010-1001","volume":"65","author":"Baer S. A.","year":"2010","journal-title":"Z. Naturforsch."},{"key":"e_1_2_6_90_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.478522"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.456153"},{"key":"e_1_2_6_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.449486"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/ct700152c"},{"key":"e_1_2_6_96_2","unstructured":"J.\u2005F. Stanton J. Gauss M.\u2005E. Harding P.\u2005G. Szalay with contributions from: A.\u2005A. Auer R.\u2005J. Bartlett U. Benedikt C. Berger D.\u2005E. Bernholdt Y.\u2005J. Bomble L. Cheng O. Christiansen M. Heckert O. Heun C. Huber T.\u2010C. Jagau D. Jonsson J. Jus\u00e9lius K. Klein W.\u2005J. Lauderdale D.\u2005A. Matthews T. Metzroth L.\u2005A. M\u00fcck D.\u2005P. O\u2032Neill D.\u2005R. Price E. Prochnow C. Puzzarini K. Ruud F. Schiffmann W. Schwalbach S. Stopkowicz A. Tajti J. V\u00e1zquez F. Wang J.\u2005D. Watts and the integral packages MOLECULE (J. Alml\u00f6f and P.\u2005R. Taylor) PROPS (P.\u2005R. Taylor) ABACUS (T. Helgaker H.\u2005J. Aa. Jensen P. J\u00f8rgensen and J. Olsen) and ECP routines by A.\u2005V. Mitin and C. van\u2005W\u00fcllen. CFOUR Coupled\u2010Cluster techniques for Computational Chemistry;2011."},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(89)85118-8"},{"key":"e_1_2_6_98_2","unstructured":"Gaussian\u200509 Revision\u2005A.1 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone B. Mennucci G.\u2005A. Petersson H. Nakatsuji M. Caricato X. Li H.\u2005P. Hratchian A.\u2005F. Izmaylov J. Bloino G. Zheng J.\u2005L. Sonnenberg M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven J.\u2005A. Montgomery Jr. J.\u2005E. Peralta F. Ogliaro M. Bearpark J.\u2005J. Heyd E. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov R. Kobayashi J. Normand K. Raghavachari A. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi N. Rega J.\u2005M. Millam M. Klene J.\u2005E. Knox J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma V.\u2005G. Zakrzewski G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg S. Dapprich A.\u2005D. Daniels \u00d6. Farkas J.\u2005B. Foresman J.\u2005V. Ortiz J. Cioslowski D.\u2005J. Fox Gaussian Inc. Wallingford CT 2009."},{"key":"e_1_2_6_99_2","unstructured":"Kohout M. DGrid. [4.6]2011 Radebeul."},{"key":"e_1_2_6_100_2","unstructured":"Oxford Diffraction. CrysalisRED. [1.171.32.15]. 2008. UK Oxford Diffraction."}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201103012","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201103012","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T09:02:06Z","timestamp":1760259726000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201103012"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,1,13]]},"references-count":101,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2012,2,13]]}},"alternative-id":["10.1002\/chem.201103012"],"URL":"https:\/\/doi.org\/10.1002\/chem.201103012","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2012,1,13]]}}}