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Up to 99\u2009% amine selectivity, 168 linear\/branched amine product ratio (<jats:italic>n\/i<\/jats:italic>), and 97.4\u2009% linear amine yield has been obtained at a substrate\/rhodium precursor ratio (S\/Rh) of 1000 with this methodology. The turnover number was achieved 6930 at 10000 S\/Rh ratio, and the <jats:italic>n\/i<\/jats:italic> can reach up to &gt;525. Several different olefins and secondary amines have been applied successfully with high chemoselectivity (99\u2009%), yield (&gt;98\u2009%), and regioselectivity (&gt;120).<\/jats:p>","DOI":"10.1002\/chem.201103073","type":"journal-article","created":{"date-parts":[[2011,11,21]],"date-time":"2011-11-21T08:54:30Z","timestamp":1321865670000},"page":"14559-14563","source":"Crossref","is-referenced-by-count":37,"title":["Highly Regioselective Hydroaminomethylation of Terminal Olefins to Linear Amines Using Rh Complexes with a Tetrabi Phosphorus 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