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Compounds <jats:bold>1<\/jats:bold>\u2013<jats:bold>7<\/jats:bold> were prepared by heating the corresponding free\u2010base corroles with POCl<jats:sub>3<\/jats:sub> at reflux in pyridine. Hexacoordinate P<jats:sup>V<\/jats:sup> complexes of <jats:italic>meso<\/jats:italic>\u2010triarylcorroles were isolated that contained two axial hydroxy groups, unlike the P<jats:sup>V<\/jats:sup> complex of 8,12\u2010diethyl\u20102,3,7,13,17,18\u2010hexamethylcorrole, which was pentacoordinate, or the P<jats:sup>V<\/jats:sup> complex of <jats:italic>meso<\/jats:italic>\u2010tetraphenylporphyrin, which was hexacoordinate with two axial chloro groups. <jats:sup>1<\/jats:sup>H and <jats:sup>31<\/jats:sup>P\u2005NMR spectroscopy in CDCl<jats:sub>3<\/jats:sub> indicated that the hexacoordinated P<jats:sup>V<\/jats:sup>\u2013<jats:italic>meso<\/jats:italic>\u2010triarylcorroles were prone to axial\u2010ligand dissociation to form pentacoordinated P<jats:sup>V<\/jats:sup>\u2013<jats:italic>meso<\/jats:italic>\u2010triarylcorroles. However, in the presence of strongly coordinating solvents, such as CH<jats:sub>3<\/jats:sub>OH, THF, and DMSO, the P<jats:sup>V<\/jats:sup>\u2013<jats:italic>meso<\/jats:italic>\u2010triarylcorroles preferred to exist in a hexacoordinated geometry in which the corresponding solvent molecules acted as axial ligands. X\u2010ray diffraction of two complexes confirmed the hexacoordination environment for P<jats:sup>V<\/jats:sup>\u2013<jats:italic>meso<\/jats:italic>\u2010triarylcorroles. Their absorption spectra in two coordinating solvents revealed that P<jats:sup>V<\/jats:sup>\u2013<jats:italic>meso<\/jats:italic>\u2010triarylcorroles showed a strong band at about 600\u2005nm together with other bands, in contrast to P<jats:sup>V<\/jats:sup>\u2013porphyrins, which showed weak bands in the visible region. These compounds were easier to oxidize and more difficult to reduce compared to P<jats:sup>V<\/jats:sup>\u2013porphyrins. These compounds were brightly fluorescent, unlike the weakly fluorescent P<jats:sup>V<\/jats:sup>\u2013porphyrins, and the quantum yields for selected P<jats:sup>V<\/jats:sup>\u2013corroles were as high as Al<jats:sup>III<\/jats:sup> and Ga<jats:sup>III<\/jats:sup> corroles, which are the best known fluorescent compounds among oligopyrrolic macrocycles.<\/jats:p>","DOI":"10.1002\/chem.201103226","type":"journal-article","created":{"date-parts":[[2012,4,3]],"date-time":"2012-04-03T11:23:43Z","timestamp":1333452223000},"page":"6386-6396","source":"Crossref","is-referenced-by-count":62,"title":["Synthesis, Structure, Spectroscopic, and Electrochemical Properties of Highly Fluorescent Phosphorus(V)\u2013<i>meso<\/i>\u2010Triarylcorroles"],"prefix":"10.1002","volume":"18","author":[{"given":"Avijit","family":"Ghosh","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mangalampalli","family":"Ravikanth","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,3,30]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b618482k"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b805230c"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424608000297"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.2174\/157019305774322716"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2008-1078687"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200206)2002:11<1735::AID-EJOC1735>3.0.CO;2-K"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200303145"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424609000668"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424604000465"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar700039y"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/jr9650001620"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1070\/RC1980v049n11ABEH002527"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1070\/RC1983v052n07ABEH002871"},{"key":"e_1_2_6_15_2","first-page":"233","volume-title":"The Porphyrin Handbook Vol. 2","author":"Erben C.","year":"2000"},{"key":"e_1_2_6_16_2","first-page":"201","volume-title":"The Porphyrin Handbook Vol. 2","author":"Paolesse R.","year":"2000"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1007\/BFb0111331"},{"key":"e_1_2_6_18_2","unstructured":"\u00a0"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp052047i"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/b507979a"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja101647t"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja202692b"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja801049t"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic901164r"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1562\/2005-06-16-RA-577"},{"key":"e_1_2_6_26_2","unstructured":"\u00a0"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990517)111:10<1530::AID-ANGE1530>3.0.CO;2-D"},{"key":"e_1_2_6_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990517)38:10<1427::AID-ANIE1427>3.0.CO;2-1"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol990739h"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/a903247i"},{"key":"e_1_2_6_30_2","unstructured":"\u00a0"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1007\/s007750100273"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1080\/02603590600666256"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424606000624"},{"key":"e_1_2_6_34_2","first-page":"2973","volume":"60","author":"Aviezer D.","year":"2000","journal-title":"Cancer Res."},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/B916590H"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(03)01356-X"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11095-005-9225-1"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja045372c"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01989e"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601399"},{"key":"e_1_2_6_40_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601399"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1039\/b911278b"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/cb900159n"},{"key":"e_1_2_6_43_2","doi-asserted-by":"crossref","unstructured":"J. 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