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Interestingly, the CO<jats:sub>3<\/jats:sub><jats:sup>2\u2212<\/jats:sup> template for <jats:bold>MOCC\u20109<\/jats:bold> was generated in situ by two\u2010step decomposition of DMF solvent. For other MOCCs, spherical or trigonal monovalent anions could also play the role of template in their formation. The template abilities of these anions in the formation of the cages were experimentally studied and are discussed for the first time. Anion exchange of <jats:bold>MOCC\u20108<\/jats:bold> was carried out and showed anion\u2010size selectivity. All of the cage\u2010like compounds emit strong luminescence at room temperature.<\/jats:p>","DOI":"10.1002\/chem.201200980","type":"journal-article","created":{"date-parts":[[2012,10,4]],"date-time":"2012-10-04T09:32:32Z","timestamp":1349343152000},"page":"16525-16530","source":"Crossref","is-referenced-by-count":18,"title":["<i>C<\/i><sub>3<i>i<\/i><\/sub>\u2010Symmetric Octanuclear Cadmium Cages: Double\u2010Anion\u2010Templated Synthesis, Formation Mechanism, and 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