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Oxidative double 1,4\u2010addition of P(O)\uf8ffH compounds to <jats:italic>p<\/jats:italic>\u2010quinones was also achieved by tuning the solvent, affording a facile synthesis of bis\u2010substituted hydroquinones with phosphorus functionality. Further studies on these reactions by using optically active H\u2010phosphinates showed that all addition reactions took place stereospecifically with retention of configuration at the phosphorus center. The findings lead to the establishment of a divergent method for the synthesis of C\u2010 and O\u2010phosphoryl hydroquinone derivatives from easily available P(O)\uf8ffH compounds.<\/jats:p>","DOI":"10.1002\/chem.201202074","type":"journal-article","created":{"date-parts":[[2012,11,9]],"date-time":"2012-11-09T13:12:54Z","timestamp":1352466774000},"page":"16902-16910","source":"Crossref","is-referenced-by-count":37,"title":["Highly Selective 1,4\u2010 and 1,6\u2010Addition of P(O)\uf8ffH Compounds to <i>p<\/i>\u2010Quinones: A Divergent Method for the Synthesis of <i>C<\/i>\u2010 and <i>O<\/i>\u2010Phosphoryl Hydroquinone Derivatives"],"prefix":"10.1002","volume":"18","author":[{"given":"Biquan","family":"Xiong","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruwei","family":"Shen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Midori","family":"Goto","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang\u2010Feng","family":"Yin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li\u2010Biao","family":"Han","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,11,9]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","first-page":"5","volume-title":"Handbook of Organophosphorus Chemistry","author":"Imamoto T.","year":"1992"},{"key":"e_1_2_6_3_2","first-page":"272","volume-title":"A Guide to Organophosphorus Chemistry","author":"Quin L. 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