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Based on the powder X\u2010ray data (PXRD) of compound <jats:bold>3<\/jats:bold> and its Zn<jats:sup>II<\/jats:sup> analogue, heating the double\u2010zigzag framework of compound <jats:bold>3<\/jats:bold> can give the polyrotaxane framework of [Cd(papo)<jats:sub>2<\/jats:sub>(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>4<\/jats:bold>) and grinding this powder sample in the presence of moisture resulted in its complete conversion back into the pure double\u2010zigzag framework. In addition, heating the double\u2010zigzag frameworks of compounds <jats:bold>1<\/jats:bold> and <jats:bold>5<\/jats:bold> can induce structural transformation into their respective polyrotaxanes, whereas grinding these solid samples in the presence of moisture did not lead to the formation of the double zigzags. Herein, we investigated the effect of the metal (from Zn<jats:sup>II<\/jats:sup> to Cd<jats:sup>II<\/jats:sup>) on the assembly process and luminescence properties, as well as on the particularly intriguing structural transformation of a series of papx\u2010based frameworks. In fact, the assembly behavior and luminescence properties of the Cd<jats:sup>II<\/jats:sup>\uf8ffpapx and Zn<jats:sup>II<\/jats:sup>\uf8ffpapx frameworks were really similar. However, both Zn<jats:sup>II<\/jats:sup>\uf8ffpapx (x=s, o) frameworks can perform reversible structural transformation, but only the Cd<jats:sup>II<\/jats:sup>\uf8ffpapo framework can do it. Therefore, a delicate metal effect on such a new structural transformation can be observed.<\/jats:p>","DOI":"10.1002\/chem.201202916","type":"journal-article","created":{"date-parts":[[2012,11,22]],"date-time":"2012-11-22T05:37:19Z","timestamp":1353562639000},"page":"16443-16449","source":"Crossref","is-referenced-by-count":13,"title":["Reversible Phase Transformation and Luminescence of Cadmium(II)\u2013Dipyridylamide\u2010Based Coordination 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