{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T19:19:29Z","timestamp":1790191169112,"version":"4.1.0"},"reference-count":92,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2013,4,24]],"date-time":"2013-04-24T00:00:00Z","timestamp":1366761600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2013,6,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Polyoxometalate (POM) complex (DODA)<jats:sub>2<\/jats:sub>[Mo<jats:sub>6<\/jats:sub>O<jats:sub>19<\/jats:sub>] with a symmetrical linear structure was prepared conveniently by replacing the tetrabutylammonium (TBA) counterions of Lindquist\u2010type cluster (TBA)<jats:sub>2<\/jats:sub>[Mo<jats:sub>6<\/jats:sub>O<jats:sub>19<\/jats:sub>] with cationic surfactant dioctadecyldimethylammonium (DODA). A helical self\u2010assembled structure of the complex was formed in dichloromethane\/propanol. The dynamically reversible transformation between helical and spherical assemblies on alternate UV irradiation and H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> oxidation was characterized by SEM, TEM, and UV\/Vis studies. The redox\u2010controlled morphology change is modulated by variation of the electrostatic interactions between the inorganic polyanion and the organic cation DODA through controlling the redox properties of the POM component, as shown by the XRD, X\u2010ray photoelectron spectroscopic, and <jats:sup>1<\/jats:sup>H NMR measurements. The strategy applied herein is a unique example of targeted smart and helical assembly of POM complexes.<\/jats:p>","DOI":"10.1002\/chem.201300309","type":"journal-article","created":{"date-parts":[[2013,4,24]],"date-time":"2013-04-24T07:58:58Z","timestamp":1366790338000},"page":"8129-8135","source":"Crossref","is-referenced-by-count":47,"title":["Redox\u2010Controlled Helical Self\u2010Assembly of a Polyoxometalate 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