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Monolayer characterization using contact\u2010angle measurements, electrochemistry, and spectroscopic ellipsometry indicate that the monolayer conversion is fast and complete. Irradiation of the receptor leads to photodimerization of the anthracenes, which induces the open\u2010to\u2010closed gating of the receptor by blocking access to the binding site. The process is thermally reversible, and polarization\u2010modulated IR reflection\u2013absorption spectroscopy indicates that photochemical closure and thermal opening of the surface\u2010bound receptors occur in 70 and 100\u2009% conversion, respectively. Affinity of the open and closed surface\u2010bound receptor was characterized by using force spectroscopy with a barbituric\u2010acid\u2010modified atomic force microscope tip.<\/jats:p>","DOI":"10.1002\/chem.201301613","type":"journal-article","created":{"date-parts":[[2013,8,8]],"date-time":"2013-08-08T11:15:50Z","timestamp":1375960550000},"page":"12748-12758","source":"Crossref","is-referenced-by-count":30,"title":["Reversible Control over Molecular Recognition in Surface\u2010Bound Photoswitchable Hydrogen\u2010Bonding Receptors: Towards Read\u2013Write\u2013Erase Molecular Printboards"],"prefix":"10.1002","volume":"19","author":[{"given":"Chih\u2010Kai","family":"Liang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Galina V.","family":"Dubacheva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thierry","family":"Buffeteau","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dominique","family":"Cavagnat","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philippe","family":"Hapiot","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruno","family":"Fabre","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James H. 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