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All of the complexes showed an intense broad structureless emission band in dichloromethane at around 680\u2013708\u2005nm, which originated from an excited state of intraligand charge transfer (<jats:sup>3<\/jats:sup>ILCT) character from the triarylamine to the bipyridine moiety. Upon introduction of the bulky and electron\u2010donating pentaphenylbenzene units attached to the aniline groups, the emission bands were found to be red shifted. The nanosecond transient absorption spectra of two selected complexes were studied, which were suggestive of the formation of an initial charge\u2010separated state. Computational studies have been performed to provide further insight into the origin of the absorption and emission. One of the rhenium(I) complexes has been utilized in the fabrication of organic light\u2010emitting diodes (OLEDs), representing the first example of the realization of deep red to near\u2010infrared rhenium(I)\u2010based OLEDs with an emission extending up to 800\u2005nm.<\/jats:p>","DOI":"10.1002\/chem.201301841","type":"journal-article","created":{"date-parts":[[2013,8,19]],"date-time":"2013-08-19T08:29:10Z","timestamp":1376900950000},"page":"13418-13427","source":"Crossref","is-referenced-by-count":82,"title":["Deep Red to Near\u2010Infrared Emitting Rhenium(I) Complexes: Synthesis, Characterization, Electrochemistry, Photophysics, and Electroluminescence Studies"],"prefix":"10.1002","volume":"19","author":[{"given":"Tao","family":"Yu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel Ping\u2010Kuen","family":"Tsang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vonika 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