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This cationic Mn<jats:sub>2<\/jats:sub> cluster templates the growth of crystals formed by an unusual achiral 3D oxalate network. The magnetic properties of this hybrid magnet are compared with those of the analogous compounds [Mn<jats:sup>III<\/jats:sup>(salen)(H<jats:sub>2<\/jats:sub>O)]<jats:sub>2<\/jats:sub>[Zn<jats:sup>II<\/jats:sup>Cr<jats:sup>III<\/jats:sup>(ox)<jats:sub>3<\/jats:sub>]<jats:sub>2<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(CH<jats:sub>3<\/jats:sub>OH)<jats:bold>\u22c5<\/jats:bold>(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>) and [In<jats:sup>III<\/jats:sup>(sal<jats:sub>2<\/jats:sub>\u2010trien)][Mn<jats:sup>II<\/jats:sup>Cr<jats:sup>III<\/jats:sup>(ox)<jats:sub>3<\/jats:sub>]<jats:bold>\u22c5<\/jats:bold>(H<jats:sub>2<\/jats:sub>O)<jats:sub>0.25<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(CH<jats:sub>3<\/jats:sub>OH)<jats:sub>0.25<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>0.25<\/jats:sub> (<jats:bold>3<\/jats:bold>), which are used as reference compounds. In <jats:bold>2<\/jats:bold> it has been shown that the magnetic isolation of the Mn<jats:sub>2<\/jats:sub> clusters provided by their insertion into a paramagnetic oxalate network of Cr<jats:sup>III<\/jats:sup> affords a SMM behavior, albeit with blocking temperatures well below 500\u2005mK even for frequencies as high as 160\u2005kHz. In <jats:bold>3<\/jats:bold> the onset of ferromagnetism in the bimetallic Mn<jats:sup>II<\/jats:sup>Cr<jats:sup>III<\/jats:sup> network is observed at <jats:italic>T<\/jats:italic><jats:sub>c<\/jats:sub>=5\u2005K. Finally, in the hybrid compound <jats:bold>1<\/jats:bold> the interaction between the two magnetic networks leads to the antiparallel arrangement of their respective magnetizations, that is, to a ferrimagnetic phase. This coupling induces also important changes on the magnetic properties of <jats:bold>1<\/jats:bold> with respect to those of the reference compounds <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold>. In particular, compound <jats:bold>1<\/jats:bold> shows a large magnetization hysteresis below 1\u2005K, which is in sharp contrast with the near\u2010reversible magnetizations that the SMMs and the oxalate ferromagnetic lattice show under the same conditions.<\/jats:p>","DOI":"10.1002\/chem.201303044","type":"journal-article","created":{"date-parts":[[2013,12,10]],"date-time":"2013-12-10T08:29:07Z","timestamp":1386664147000},"page":"1669-1676","source":"Crossref","is-referenced-by-count":46,"title":["Insertion of a Single\u2010Molecule Magnet inside a Ferromagnetic Lattice Based on a 3D Bimetallic Oxalate Network: Towards Molecular Analogues of Permanent Magnets"],"prefix":"10.1002","volume":"20","author":[{"given":"Miguel","family":"Clemente\u2010Le\u00f3n","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eugenio","family":"Coronado","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carlos J.","family":"G\u00f3mez\u2010Garc\u00eda","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maurici","family":"L\u00f3pez\u2010Jord\u00e0","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agust\u00edn","family":"Cam\u00f3n","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ana","family":"Repoll\u00e9s","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fernando","family":"Luis","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,12,10]]},"reference":[{"key":"e_1_2_6_1_2","volume-title":"Permanent Magnetism","author":"Skomski R.","year":"1999"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.328987"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.333572"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00044a004"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(20000204)6:3<552::AID-CHEM552>3.0.CO;2-U"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.2001.9169"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1992.1975"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39940001551"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic950703v"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic960838g"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic051373"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/B602250B"},{"key":"e_1_2_6_15_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic8021003"},{"key":"e_1_2_6_16_2","unstructured":"\u00a0"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00062a004"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00100a016"},{"key":"e_1_2_6_19_2","first-page":"4141","volume":"37","author":"Hern\u00e1ndez\u2010Molina M.","year":"1998","journal-title":"Inorg. 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