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The cascade reaction that leads to the alkyl cinnamates occurs through two oxidation steps: the selective oxidation of cinnamyl alcohol to cinnamaldehyde, followed by oxidation of the hemiacetal that results from the base\u2010catalysed reaction of cinnamaldehyde with an aliphatic alcohol. The rate constants for the two steps were evaluated in the temperature range 10\u201345\u2009\u00b0C. The cinnamyl alcohol oxidation is faster than the oxidative esterification of cinnamaldehyde with methanol, ethanol, 2\u2010propanol, 1\u2010butanol, 1\u2010hexanol or 1\u2010octanol. The rate constants of the latter reaction are pseudo\u2010zero order with respect to the aliphatic alcohol and decrease as the bulkiness of the alcohol is increased. The activation energy (<jats:italic>E<\/jats:italic><jats:sub>a<\/jats:sub>) for the two oxidation steps was calculated for esterification of cinnamyl alcohol with 1\u2010butanol (<jats:italic>E<\/jats:italic><jats:sub>a<\/jats:sub>=57.8\u00b111.5 and 62.7\u00b116.7\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup> for the first and second step, respectively). The oxidative esterification of cinnamyl alcohol with 2\u2010phenylethanol follows pseudo\u2010first\u2010order kinetics with respect to 2\u2010phenylethanol and is faster than observed for other alcohols because of fast diffusion of the aromatic alcohol in the crystalline phase of the support. The kinetic investigation allowed us to assess the role of the polymer support in the determination of both high activity and selectivity in the title reaction.<\/jats:p>","DOI":"10.1002\/chem.201303880","type":"journal-article","created":{"date-parts":[[2014,3,18]],"date-time":"2014-03-18T18:42:08Z","timestamp":1395168128000},"page":"5478-5486","source":"Crossref","is-referenced-by-count":51,"title":["Highly Efficient Direct Aerobic Oxidative Esterification of Cinnamyl Alcohol with Alkyl Alcohols Catalysed by Gold Nanoparticles Incarcerated in a Nanoporous Polymer Matrix: A Tool for Investigating the Role of the Polymer Host"],"prefix":"10.1002","volume":"20","author":[{"given":"Antonio","family":"Buonerba","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Annarita","family":"Noschese","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alfonso","family":"Grassi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,18]]},"reference":[{"key":"e_1_2_6_1_2","first-page":"403","volume":"3","author":"Sharma P.","year":"2011","journal-title":"J. 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