{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:35:36Z","timestamp":1786977336967,"version":"build-2736575974"},"reference-count":52,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2013,12,16]],"date-time":"2013-12-16T00:00:00Z","timestamp":1387152000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2014,1,13]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A new structural arrangement Te\n                    <jats:sub>3<\/jats:sub>\n                    (RP\n                    <jats:sup>III<\/jats:sup>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    and the first crystal structures of organophosphorus(III)\u2013tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Te\n                    <jats:sub>\n                      <jats:italic>m<\/jats:italic>\n                    <\/jats:sub>\n                    (P\n                    <jats:sup>III<\/jats:sup>\n                    R)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (\n                    <jats:italic>m<\/jats:italic>\n                    =1:\n                    <jats:italic>n<\/jats:italic>\n                    =2, R=OMes* (Mes*=supermesityl or 2,4,6\u2010tri\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butylphenyl);\n                    <jats:italic>n<\/jats:italic>\n                    =3, R=adamantyl (Ad);\n                    <jats:italic>n<\/jats:italic>\n                    =4, R=ferrocene (Fc);\n                    <jats:italic>m<\/jats:italic>\n                    =\n                    <jats:italic>n<\/jats:italic>\n                    =3: R=trityl (Trt), Mesor by the installation of a P\n                    <jats:sup>V<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    anchor in RP\n                    <jats:sup>III<\/jats:sup>\n                    [TeP\n                    <jats:sup>V<\/jats:sup>\n                    (\n                    <jats:italic>t<\/jats:italic>\n                    BuN)(\u03bc\u2010N\n                    <jats:italic>t<\/jats:italic>\n                    Bu)]\n                    <jats:sub>2<\/jats:sub>\n                    (R=Ad,\n                    <jats:italic>t<\/jats:italic>\n                    Bu).\n                  <\/jats:p>","DOI":"10.1002\/chem.201303884","type":"journal-article","created":{"date-parts":[[2013,12,16]],"date-time":"2013-12-16T15:30:03Z","timestamp":1387207803000},"page":"704-712","source":"Crossref","is-referenced-by-count":22,"title":["Isolatable Organophosphorus(III)\u2013Tellurium Heterocycles"],"prefix":"10.1002","volume":"20","author":[{"given":"Andreas","family":"Nordheider","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tristram","family":"Chivers","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oliver","family":"Sch\u00f6n","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin","family":"Karaghiosoff","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kasun S.","family":"Athukorala\u2005Arachchige","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandra M. Z.","family":"Slawin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J. Derek","family":"Woollins","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,12,16]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)90895-5"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800572"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800572"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201006081"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006081"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc40515j"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0031-1290665"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2003-41447"},{"key":"e_1_2_6_8_2","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","volume-title":"Topics in Current Chemistry: Organoselenium Chemistry, Modern Developments in Organic Synthesis","year":"2000"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001103)112:21<3890::AID-ANGE3890>3.0.CO;2-L"},{"key":"e_1_2_6_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001103)39:21<3740::AID-ANIE3740>3.0.CO;2-N"},{"key":"e_1_2_6_11_2","doi-asserted-by":"crossref","first-page":"256","DOI":"10.1039\/9781849730471","volume-title":"Inorganic Rings and Polymers of the p\u2010Block Elements: From Fundamentals to Applications","author":"Chivers T.","year":"2009"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19830951232"},{"key":"e_1_2_6_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198309831"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19936190619"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426500108546588"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200900324"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/hc.20449"},{"key":"e_1_2_6_17_2","unstructured":"The higher thermal robustness of the adamantyl (Ad) compared to thetBu derivative enabled the first structural characterization of a selenium diimide RN\uf8feSe\uf8feNR;"},{"key":"e_1_2_6_18_2","first-page":"2332","author":"Maaninen T.","year":"2002","journal-title":"Chem. Commun."},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/a607889c"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/b000620n"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426509208038351"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc00827c"},{"key":"e_1_2_6_23_2","unstructured":"At low temperature resonances in the31P\u2005NMR spectrum were observed which indicated the presence of a 1 3\u2010ditellura\u20102 4 5\u2010triphospholane consistent with an ABM spectrum (ignoring the125Te\u2010containing isotopomers). At room temperature the signals disappeared which precluded further characterization. The spin simulation and spectrum of the compound are displayed in the Supporting Information. The calculated values of the NMR parameters are comparable to those of du\u2005Mont and Severengiz Te2(tBuP)3(Ref.\u2005[7]). A reinvestigation of Te2(tBuP)3showed three distinct phosphorus signals in the31P\u2005NMR consistent with the suggestedcis\u2010structure (Ref.\u2005[7]). Similarly Karaghiosoff and co\u2010workers reported Te2(CF3P)3(Ref.\u2005[9])."},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_6_25_2","unstructured":"All spin simulations were performed by using MestReNova\u2005v7.1.1\u20109649 Mestrelab Research S.L. 2012."},{"key":"e_1_2_6_26_2","unstructured":"Negative signs of the coupling constants result from the iterative fitting of the spectrum."},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19911240103"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2DT32716C"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19946200128"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39820000691"},{"key":"e_1_2_6_31_2","unstructured":"(OPNPr\u20322)3adopts a boat conformation:"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19800920911"},{"key":"e_1_2_6_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198007091"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00279a047"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020916)114:18<3618::AID-ANGE3618>3.0.CO;2-Q"},{"key":"e_1_2_6_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020916)41:18<3468::AID-ANIE3468>3.0.CO;2-W"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300234"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic020562e"},{"key":"e_1_2_6_37_2","unstructured":"Disordered structure and crystallographic data including bond lengths and angles for7\u2009aare deposited in the Supporting Information."},{"key":"e_1_2_6_38_2","unstructured":"Investigations of the coordination chemistry of acyclic Te(PR2)2ligands have been limited to theP P\u2032\u2010chelated complexes [M(CO)4][Te(PtBu2)2] (M=Cr Mo W)"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19851180425"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1080\/03086648308075970"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19851181233"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01430a018"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1987-33426"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(90)80007-M"},{"key":"e_1_2_6_45_2","first-page":"118","volume":"3","author":"Yoshifuji M.","year":"1996","journal-title":"Synth. 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