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In contrast to other N,P ligand complexes, which require weakly coordinating solvents, such as dichloromethane, these catalysts perform well in more ecofriendly THF or 2\u2010MeTHF. Their synthetic potential was demonstrated with the formal total synthesis of four bisabolane sesquiterpenes.<\/jats:p>","DOI":"10.1002\/chem.201303915","type":"journal-article","created":{"date-parts":[[2014,1,30]],"date-time":"2014-01-30T08:47:23Z","timestamp":1391071643000},"page":"2440-2444","source":"Crossref","is-referenced-by-count":27,"title":["Iridium\u2010Catalyzed Asymmetric Hydrogenation of 3,3\u2010Disubstituted Allylic Alcohols in Ethereal Solvents"],"prefix":"10.1002","volume":"20","author":[{"given":"Maurizio","family":"Bernasconi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vincenzo","family":"Ramella","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Paolo","family":"Tosatti","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andreas","family":"Pfaltz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,1,30]]},"reference":[{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar700140m"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00239a065"},{"key":"e_1_2_4_3_2","unstructured":"\u00a0"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0500131"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar200145q"},{"key":"e_1_2_4_6_2","unstructured":"\u00a0"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja057178b"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601529"},{"key":"e_1_2_4_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601529"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981016)110:20<3047::AID-ANGE3047>3.0.CO;2-F"},{"key":"e_1_2_4_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981102)37:20<2897::AID-ANIE2897>3.0.CO;2-8"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja801706s"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2010.03.023"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2011.02.021"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja204948k"},{"key":"e_1_2_4_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0464241"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja016011p"},{"key":"e_1_2_4_16_2","unstructured":"\u00a0"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol990961m"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/0957-4166(95)00082-Z"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00155a034"},{"key":"e_1_2_4_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107910"},{"key":"e_1_2_4_19_4","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107910"},{"key":"e_1_2_4_20_2","first-page":"967","volume-title":"Organotransition Metal Chemistry: From Bonding to Catalysis","author":"Hartwig J. 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