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Here, the one\u2010dimensional coordination polymers [M(\u03bc,\u03b7<jats:sup>5<\/jats:sup>:\u03b7<jats:sup>1<\/jats:sup>\u2010E<jats:sub>5<\/jats:sub>FeCp*)<jats:sub>3<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>[TEF]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (E=P, M=Tl (<jats:bold>3\u2009a<\/jats:bold>), In (<jats:bold>3\u2009b<\/jats:bold>), Ga (<jats:bold>3\u2009c<\/jats:bold>); E=As, M=Tl (<jats:bold>4\u2009a<\/jats:bold>), In (<jats:bold>4\u2009b<\/jats:bold>)) are obtained as sole products in good yields. All products were analyzed by single\u2010crystal X\u2010ray diffraction, revealing a similar assembly of the products with \u03b7<jats:sup>5<\/jats:sup>\u2010bound E<jats:sub>5<\/jats:sub> ligands and very weak \u03c3\u2010interactions between one P or As atom of the ring to the neighbored Group 13 metal cation. By exchanging the [TEF] anion of <jats:bold>4\u2009a<\/jats:bold> for the larger [FAl] anion ([FAl]=[FAl{OC<jats:sub>6<\/jats:sub>F<jats:sub>10<\/jats:sub>(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)}<jats:sub>3<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>), the coordination compound [Tl{(\u03b7<jats:sup>5<\/jats:sup>\u2010As<jats:sub>5<\/jats:sub>)FeCp*}<jats:sub>3<\/jats:sub>][FAl] (<jats:bold>5<\/jats:bold>) without any \u03c3\u2010interactions of the As<jats:sub>5<\/jats:sub>\u2010ring is obtained. All products are readily soluble in CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> and exhibit a dynamic coordination behavior in solution, which is supported by NMR spectroscopy and ESI\u2010MS spectrometry as well as by osmometric molecular\u2010weight determination. For a better understanding of the proceeding equilibrium DFT calculations of the cationic complexes were performed for the gas phase and in solution. Furthermore, the <jats:sup>31<\/jats:sup>P{<jats:sup>1<\/jats:sup>H} magic\u2010angle spinning (MAS) NMR spectra of <jats:bold>3\u2009a\u2013c<\/jats:bold> are presented and the first crystal structure of the starting material <jats:bold>2<\/jats:bold> was determined.<\/jats:p>","DOI":"10.1002\/chem.201304466","type":"journal-article","created":{"date-parts":[[2014,2,24]],"date-time":"2014-02-24T16:27:52Z","timestamp":1393259272000},"page":"3759-3768","source":"Crossref","is-referenced-by-count":50,"title":["Complexes of Monocationic Group\u200513 Elements with Pentaphospha\u2010 and Pentaarsaferrocene"],"prefix":"10.1002","volume":"20","author":[{"given":"Martin","family":"Fleischmann","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Welsch","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hannes","family":"Krauss","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Monika","family":"Schmidt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Bodensteiner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eugenia V.","family":"Peresypkina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marek","family":"Sierka","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Gr\u00f6ger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,2,24]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr960053s"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar970224v"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9601324"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990110s"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0103672"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar010142d"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351797"},{"key":"e_1_2_6_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351797"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1129830"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1124985"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/B612726F"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1138748"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703371"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703371"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200702075"},{"key":"e_1_2_6_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702075"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/om800419s"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805949"},{"key":"e_1_2_6_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805949"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901443"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805028"},{"key":"e_1_2_6_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805028"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1175313"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.873"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja102633e"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1007\/128_2011_280"},{"key":"e_1_2_6_23_2","first-page":"59","volume":"99","author":"Scherer O. 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