{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T02:47:55Z","timestamp":1792032475499,"version":"4.4.0"},"reference-count":20,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2014,3,19]],"date-time":"2014-03-19T00:00:00Z","timestamp":1395187200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2014,4,25]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>It is well accepted that metallic tin as a discharge (reduction) product of SnO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> cannot be electrochemically oxidized below 3.00\u2005V versus Li<jats:sup>+<\/jats:sup>\/Li<jats:sup>0<\/jats:sup> due to the high stability of Li<jats:sub>2<\/jats:sub>O, though a similar oxidation can usually occur for a transition metal formed from the corresponding oxide. In this work, nanosized Ni<jats:sub>2<\/jats:sub>SnO<jats:sub>4<\/jats:sub> and NiO\/SnO<jats:sub>2<\/jats:sub> nanocomposite were synthesized by coprecipitation reactions and subsequent heat treatment. Owing to the catalytic effect of nanosized metallic nickel, metallic tin can be electrochemically oxidized to SnO<jats:sub>2<\/jats:sub> below 3.00\u2005V. As a result, the reversible lithium\u2010storage capacities of the nanocomposite reach 970\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> or above, much higher than the theoretical capacity (ca. 750\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup>) of SnO<jats:sub>2<\/jats:sub>, NiO, or their composites. These findings extend the well\u2010known electrochemical conversion reaction to non\u2010transition\u2010metal compounds and may have important applications, for example, in constructing high\u2010capacity electrode materials and efficient catalysts.<\/jats:p>","DOI":"10.1002\/chem.201304817","type":"journal-article","created":{"date-parts":[[2014,3,19]],"date-time":"2014-03-19T22:43:51Z","timestamp":1395269031000},"page":"5487-5491","source":"Crossref","is-referenced-by-count":32,"title":["Transition\u2010Metal\u2010Catalyzed Oxidation of Metallic Sn in NiO\/SnO<sub>2<\/sub> Nanocomposite"],"prefix":"10.1002","volume":"20","author":[{"given":"Chunxiu","family":"Hua","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangpeng","family":"Fang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoxiang","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liquan","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,19]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/35035045"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1497981"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1370962"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201202601"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2nr11966h"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.276.5317.1395"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1838211"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1837740"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2012.10.068"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2013.01.030"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b9nr00102f"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2EE23330D"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ra20527k"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02375556"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm03132a"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2010.04.003"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp111015j"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b908149f"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2013.02.049"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2012.07.020"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201304817","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201304817","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T13:08:07Z","timestamp":1760274487000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201304817"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,3,19]]},"references-count":20,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2014,4,25]]}},"alternative-id":["10.1002\/chem.201304817"],"URL":"https:\/\/doi.org\/10.1002\/chem.201304817","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,3,19]]}}}