{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:37:28Z","timestamp":1785890248154,"version":"3.56.0"},"reference-count":100,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2014,3,18]],"date-time":"2014-03-18T00:00:00Z","timestamp":1395100800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation","doi-asserted-by":"crossref","award":["91213302"],"award-info":[{"award-number":["91213302"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation","doi-asserted-by":"crossref","award":["21272102"],"award-info":[{"award-number":["21272102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Key National S&T Program \u201cMajor New Drug Development\u201d of the Ministry of Science and Technology of China","award":["2012ZX09504001-003"],"award-info":[{"award-number":["2012ZX09504001-003"]}]},{"name":"Program for Changjiang Scholars and Innovative Research Team in University","award":["PCSIRT: IRT1137"],"award-info":[{"award-number":["PCSIRT: IRT1137"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2014,4,22]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Asymmetric cyanation of trimethylsilyl cyanide (TMSCN) with \u03b1,\u03b2\u2010unsaturated amides and ketones, respectively, catalyzed by bifunctional mononuclear 1,1\u2032\u2010bi\u20102\u2010naphthol (BINOL)\u2013Mg and binuclear bis(prophenol)\u2013Mg catalysts was realized. A series of synthetically important 1,4\u2010cyano products were obtained with good to high enantioselectivities (up to 97\u2009%\u2005<jats:italic>ee<\/jats:italic>).<\/jats:p>","DOI":"10.1002\/chem.201304835","type":"journal-article","created":{"date-parts":[[2014,3,18]],"date-time":"2014-03-18T18:57:41Z","timestamp":1395169061000},"page":"4911-4915","source":"Crossref","is-referenced-by-count":54,"title":["Magnesium Complexes as Highly Effective Catalysts for Conjugate Cyanation of \u03b1,\u03b2\u2010Unsaturated Amides and Ketones"],"prefix":"10.1002","volume":"20","author":[{"given":"Jinlong","family":"Zhang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xihong","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,18]]},"reference":[{"key":"e_1_2_4_1_2","unstructured":"\u00a0"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0006-2952(74)90033-1"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0082(78)90009-6"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0082(91)90036-Z"},{"key":"e_1_2_4_5_2","unstructured":"\u00a0"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo048199b"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8044376"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol8017352"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja034635k"},{"key":"e_1_2_4_10_2","unstructured":"For examples see:"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046653n"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja043424s"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2007.02.081"},{"key":"e_1_2_4_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704461"},{"key":"e_1_2_4_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704461"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja801201r"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1035286"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol100169r"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201100939"},{"key":"e_1_2_4_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201100939"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc35528k"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201278"},{"key":"e_1_2_4_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol403545b"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201001107"},{"key":"e_1_2_4_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1OB05899A"},{"key":"e_1_2_4_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201300215"},{"key":"e_1_2_4_25_2","unstructured":"For phase\u2010transfer\u2010catalyzed asymmetric conjugate cyanation see:"},{"key":"e_1_2_4_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105536"},{"key":"e_1_2_4_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105536"},{"key":"e_1_2_4_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201278"},{"key":"e_1_2_4_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol400143m"},{"key":"e_1_2_4_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201300406"},{"key":"e_1_2_4_30_2","unstructured":"For reviews in catalysis with alkaline earth\u2010metal complexes:"},{"key":"e_1_2_4_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901261"},{"key":"e_1_2_4_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901261"},{"key":"e_1_2_4_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003659"},{"key":"e_1_2_4_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100204f"},{"key":"e_1_2_4_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar100103h"},{"key":"e_1_2_4_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar100101b"},{"key":"e_1_2_4_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201200231"},{"key":"e_1_2_4_37_2","unstructured":"MgII\u2013BINOLates have received little attention in asymmetric catalysis. 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