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These activated iodosylbenzene monomers are all non\u2010hygroscopic shelf\u2010storable reagents, but they maintain high oxidizing ability in water. The complexes are effective for the oxidation of phenols, sulfides, olefins, silyl enol ethers, and alkyl(trifluoro)borates under mild conditions. Furthermore, hydroxy\u2010\u03bb<jats:sup>3<\/jats:sup>\u2010iodane\u2013[18]crown\u20106 complexes serve as efficient progenitors for the synthesis of diaryl\u2010, vinyl\u2010, and alkynyl\u2010\u03bb<jats:sup>3<\/jats:sup>\u2010iodanes in water. Other less polar organic solvents, such as methanol, acetonitrile, and dichloromethane, are also usable in some cases.<\/jats:p>","DOI":"10.1002\/chem.201304961","type":"journal-article","created":{"date-parts":[[2014,3,18]],"date-time":"2014-03-18T19:43:30Z","timestamp":1395171810000},"page":"5447-5453","source":"Crossref","is-referenced-by-count":34,"title":["Reactivity of Hydroxy\u2010 and Aquo(hydroxy)\u2010\u03bb<sup>3<\/sup>\u2010iodane\u2013Crown Ether Complexes"],"prefix":"10.1002","volume":"20","author":[{"given":"Kazunori","family":"Miyamoto","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yukie","family":"Yokota","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takashi","family":"Suefuji","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kentaro","family":"Yamaguchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomoyuki","family":"Ozawa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masahito","family":"Ochiai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,18]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"The Organic Chemistry of Polycoordinated Iodine","author":"Varvoglis A.","year":"1992"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr010003"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00498a040"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(98)00229-6"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(98)00023-6"},{"key":"e_1_2_6_7_2","unstructured":"\u00a0"},{"key":"e_1_2_6_8_2","first-page":"551","author":"Zhao X. 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