{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T01:17:21Z","timestamp":1789780641858,"version":"4.0.1"},"reference-count":78,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2014,3,28]],"date-time":"2014-03-28T00:00:00Z","timestamp":1395964800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2014,5,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Two unique systems based on low\u2010coordinate main group elements that activate P<jats:sub>4<\/jats:sub> are shown to quantitatively release the phosphorus cage upon short exposure to UV light. This reactivity marks the first reversible reactivity of P<jats:sub>4<\/jats:sub>, and the germanium system can be cycled 5\u2005times without appreciable loss in activity. Theoretical calculations reveal that the LUMO is antibonding with respect to the main group element\u2013phosphorus bonds and bonding with respect to reforming the P<jats:sub>4<\/jats:sub> tetrahedron, providing a rationale for this unprecedented activity, and suggesting that the process is tunable based on the substituents.<\/jats:p>","DOI":"10.1002\/chem.201402031","type":"journal-article","created":{"date-parts":[[2014,3,28]],"date-time":"2014-03-28T19:07:20Z","timestamp":1396033640000},"page":"6739-6744","source":"Crossref","is-referenced-by-count":92,"title":["Reversible, Photoinduced Activation of P<sub>4<\/sub> by Low\u2010Coordinate Main Group Compounds"],"prefix":"10.1002","volume":"20","author":[{"given":"Jonathan W.","family":"Dube","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cameron M. E.","family":"Graham","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charles L. B.","family":"Macdonald","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zachary D.","family":"Brown","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philip P.","family":"Power","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul J.","family":"Ragogna","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,28]]},"reference":[{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903708"},{"key":"e_1_2_4_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903708"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00388C"},{"key":"e_1_2_4_4_2","unstructured":"\u00a0"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200017h"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar2000875"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20130134"},{"key":"e_1_2_4_10_2","unstructured":"\u00a0"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja808506t"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901636"},{"key":"e_1_2_4_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901636"},{"key":"e_1_2_4_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176443"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105097"},{"key":"e_1_2_4_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105097"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201303705"},{"key":"e_1_2_4_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201303705"},{"key":"e_1_2_4_17_2","unstructured":"\u00a0"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/b510917e"},{"key":"e_1_2_4_21_2","unstructured":"\u00a0"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803971"},{"key":"e_1_2_4_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803971"},{"key":"e_1_2_4_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200906633"},{"key":"e_1_2_4_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200906633"},{"key":"e_1_2_4_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500707"},{"key":"e_1_2_4_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500707"},{"key":"e_1_2_4_25_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1168260"},{"key":"e_1_2_4_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906294m"},{"key":"e_1_2_4_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja802080m"},{"key":"e_1_2_4_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic2014607"},{"key":"e_1_2_4_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201306492"},{"key":"e_1_2_4_28_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201306492"},{"key":"e_1_2_4_29_2","unstructured":"\u00a0"},{"key":"e_1_2_4_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17449a"},{"key":"e_1_2_4_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_4_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_4_33_2","unstructured":"\u00a0"},{"key":"e_1_2_4_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353406"},{"key":"e_1_2_4_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353406"},{"key":"e_1_2_4_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200701203"},{"key":"e_1_2_4_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200701203"},{"key":"e_1_2_4_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105610"},{"key":"e_1_2_4_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105610"},{"key":"e_1_2_4_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005866"},{"key":"e_1_2_4_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005866"},{"key":"e_1_2_4_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200502865"},{"key":"e_1_2_4_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200502865"},{"key":"e_1_2_4_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic1010743"},{"key":"e_1_2_4_40_2","unstructured":"\u00a0"},{"key":"e_1_2_4_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804903"},{"key":"e_1_2_4_41_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804903"},{"key":"e_1_2_4_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc02418j"},{"key":"e_1_2_4_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906878q"},{"key":"e_1_2_4_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic2013304"},{"key":"e_1_2_4_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902344"},{"key":"e_1_2_4_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902344"},{"key":"e_1_2_4_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703055"},{"key":"e_1_2_4_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703055"},{"key":"e_1_2_4_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc42041h"},{"key":"e_1_2_4_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301137"},{"key":"e_1_2_4_48_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301137"},{"key":"e_1_2_4_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077296u"},{"key":"e_1_2_4_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201204337"},{"key":"e_1_2_4_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302914"},{"key":"e_1_2_4_51_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302914"},{"key":"e_1_2_4_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/om960929l"},{"key":"e_1_2_4_53_2","unstructured":"For full details including NMR spectra see the Supporting Information."},{"key":"e_1_2_4_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja207538g"},{"key":"e_1_2_4_55_2","unstructured":"CCDC\u2010991637 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_4_56_2","unstructured":"UV light was generated by a low\u2010pressure high\u2010intensity single\u2010arc mercury lamp. The predominant wavelength produced is 254\u2005nm. The power generated was measured to be 23.2\u2005mW over the course of a 15\u2005min irradiation cycle."},{"key":"e_1_2_4_57_2","unstructured":"\u00a0"},{"key":"e_1_2_4_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja302963p"},{"key":"e_1_2_4_59_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1470"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201402031","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201402031","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:21:42Z","timestamp":1760286102000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201402031"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,3,28]]},"references-count":78,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2014,5,26]]}},"alternative-id":["10.1002\/chem.201402031"],"URL":"https:\/\/doi.org\/10.1002\/chem.201402031","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,3,28]]}}}