{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T13:55:46Z","timestamp":1772805346236,"version":"3.50.1"},"reference-count":68,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2014,7,2]],"date-time":"2014-07-02T00:00:00Z","timestamp":1404259200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"crossref","award":["21201110"],"award-info":[{"award-number":["21201110"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Special Funding of China Postdoctoral Science Foundation","award":["2013T60663"],"award-info":[{"award-number":["2013T60663"]}]},{"name":"Research Award Fund for Outstanding Middle-aged and Young Scientist of Shandong Province","award":["BS2013L010"],"award-info":[{"award-number":["BS2013L010"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2014,8,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The long\u2010persistent phosphorescent metal\u2013organic framework (MOF) is a kind of highly desirable but rare material. Here, two new molecular MOF materials, {[Zn(tipa)Cl]<jats:bold>\u22c5<\/jats:bold>NO<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>2\u2009DMF}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>1<\/jats:bold>) and {[Cd<jats:sub>2<\/jats:sub>(tipa)<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>]<jats:bold>\u22c5<\/jats:bold>6\u2009DMF}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>2<\/jats:bold>) (tipa=tri(4\u2010imidazolylphenyl)amine), which have 3D twofold interpenetrated (<jats:bold>utp<\/jats:bold>) and 2D noninterpenetrated (<jats:bold>kgd<\/jats:bold>) topologies, respectively, are reported. They exhibit unexpected long\u2010persistent emissions yet reported: At 77\u2005K, they persist in glowing after stopping the UV irradiation on a timescale up to seconds at 77\u2005K, which can be detected by the naked eye (ca. 2\u2005s). Compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> also undergo single\u2010crystal\u2010to\u2010single\u2010crystal (SC\u2010SC) transformations through different routes; a simple anion\u2010exchange route for <jats:bold>1<\/jats:bold> and a complicated replacement of \u03bc<jats:sub>1<\/jats:sub>\u2010Cl<jats:sup>\u2212<\/jats:sup> ions by DMF molecules accompanying I<jats:sub>3<\/jats:sub><jats:sup>\u2212<\/jats:sup> captured in the void for <jats:bold>2<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.201402211","type":"journal-article","created":{"date-parts":[[2014,7,2]],"date-time":"2014-07-02T16:30:46Z","timestamp":1404318646000},"page":"10093-10098","source":"Crossref","is-referenced-by-count":153,"title":["Unprecedented Second\u2010Timescale Blue\/Green Emissions and Iodine\u2010Uptake\u2010Induced Single\u2010Crystal\u2010to\u2010Single\u2010Crystal Transformation in Zn<sup>II<\/sup>\/Cd<sup>II<\/sup> Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"20","author":[{"given":"Shuai","family":"Yuan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yong\u2010Kai","family":"Deng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Di","family":"Sun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,7,2]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981116)110:22<3250::AID-ANGE3250>3.0.CO;2-1"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981204)37:22<3084::AID-ANIE3084>3.0.CO;2-W"},{"key":"e_1_2_6_2_2","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0496422"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja002956f"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0702427104"},{"key":"e_1_2_6_6_2","unstructured":"\u00a0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200205j"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200190s"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.834"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200139g"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.678"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200252n"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1192"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200101d"},{"key":"e_1_2_6_15_2","unstructured":"\u00a0"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja903947b"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja211271m"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802352m"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja211230p"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2108036"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja209327q"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/B617136B"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200503778"},{"key":"e_1_2_6_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503778"},{"key":"e_1_2_6_24_2","doi-asserted-by":"crossref","unstructured":"V.\u2005A. Blatov Struct. Chem.\u00ad2012 23 955. TOPOS software is available for download at:http:\/\/www.topos.samsu.ru.","DOI":"10.1007\/s11224-012-0013-3"},{"key":"e_1_2_6_25_2","unstructured":"M. O\u2019Keeffe Reticular Chemistry Structure Resource seehttp:\/\/rcsr.anu.edu.au\/nets\/."},{"key":"e_1_2_6_26_2","volume-title":"Three\u2010dimensional Nets, Polyhedra","author":"Wells A. F.","year":"1977"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/B409722J"},{"key":"e_1_2_6_28_2","unstructured":"A.\u2005L. Spek Implemented as the PLATON Procedure a Multipurpose Crystallographic Tool Utrecht University Utrecht The Netherlands 1998."},{"key":"e_1_2_6_29_2","volume-title":"Further studies of three\u2010dimensional nets","author":"Wells A. F.","year":"1979"},{"key":"e_1_2_6_30_2","first-page":"407","volume":"210","author":"Koch E.","year":"1995","journal-title":"Kristall."},{"key":"e_1_2_6_31_2","unstructured":"\u00a0"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20011119)7:22<4805::AID-CHEM4805>3.0.CO;2-3"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic060276t"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/B702988H"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/b700569e"},{"key":"e_1_2_6_36_2","unstructured":"\u00a0"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/b923998g"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201000218"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9639473"},{"key":"e_1_2_6_40_2","unstructured":"\u00a0"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic300816r"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic300940k"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/B711457E"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/B301806G"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/b408000a"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600980"},{"key":"e_1_2_6_47_2","unstructured":"\u00a0"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja908293n"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja211381e"},{"key":"e_1_2_6_50_2","unstructured":"\u00a0"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460076"},{"key":"e_1_2_6_51_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460076"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200600676"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0204101"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC04724D"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.1837067"},{"key":"e_1_2_6_56_2","unstructured":"\u00a0"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.12.017"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic034185x"},{"key":"e_1_2_6_59_2","unstructured":"Bruker APEX2; Bruker AXS Inc. Madison WI 2010."},{"key":"e_1_2_6_60_2","unstructured":"Bruker SAINT Data Reduction Software Bruker AXS Inc. Madison WI 2009."},{"key":"e_1_2_6_61_2","unstructured":"Sheldrick G.\u2005M.SADABS Program for Empirical Absorption Correction University of Gottingen Gottingen Germany 2008."},{"key":"e_1_2_6_62_2","unstructured":"\u00a0"},{"key":"e_1_2_6_63_2","unstructured":"Sheldrick G.\u2005M.SHELXL\u201097 Program for the Refinement of Crystal University of Gottingen Gottingen Germany 1997;"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767390000277"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201402211","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201402211","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:54:59Z","timestamp":1760291699000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201402211"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,7,2]]},"references-count":68,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2014,8,4]]}},"alternative-id":["10.1002\/chem.201402211"],"URL":"https:\/\/doi.org\/10.1002\/chem.201402211","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,7,2]]}}}