{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T23:01:05Z","timestamp":1792710065791,"version":"4.5.0"},"reference-count":47,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2014,11,4]],"date-time":"2014-11-04T00:00:00Z","timestamp":1415059200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,1,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A series of alluaudite Na<jats:sub>2<\/jats:sub>Fe<jats:sub>3\u2212<jats:italic>x<\/jats:italic><\/jats:sub>Mn<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> microcompounds, which self\u2010assembled from primary nanorods, were prepared successfully through a solvothermal method. As a promising candidate cathode for sodium\u2010ion batteries, it is necessary to obtain a deeper understanding of the relationship between the structure and physicochemical properties of these materials. The local electronic and geometric environments were systematically investigated, for the first time, by using a combination of soft\/hard X\u2010ray absorption, IR, and M\u00f6ssbauer spectroscopy. The results show that the electrochemical performance is not only associated with morphology, but also with the electronic and crystalline structure. With the introduction of manganese into the lattice, the long\u2010range order maintains the isostructural framework and the lattice parameters expand as expected. However, for short\u2010range order, PO<jats:sub>4<\/jats:sub> tetrahedra and MO<jats:sub>6<\/jats:sub> octahedra (M=Fe and Mn) become more severely distorted as a function of Mn concentration. Meanwhile, larger MnO<jats:sub>6<\/jats:sub> octahedra will compress the space of FeO<jats:sub>6<\/jats:sub> octahedra, which will result in stronger core\/electron\u2013electron interactions for Fe, as characterized by hard\/soft X\u2010ray absorption spectra. These slight changes in the electronic and local structures lead to different electrochemical performances with changes to the manganese content. Moreover, other physicochemical properties, such as magnetic behavior, are also confirmed to be correlated with these different electron interactions and local geometric environments.<\/jats:p>","DOI":"10.1002\/chem.201403062","type":"journal-article","created":{"date-parts":[[2014,11,4]],"date-time":"2014-11-04T15:57:48Z","timestamp":1415116668000},"page":"851-860","source":"Crossref","is-referenced-by-count":68,"title":["Self\u2010Assembled Alluaudite Na<sub>2<\/sub>Fe<sub>3\u2212<i>x<\/i><\/sub>Mn<sub><i>x<\/i><\/sub>(PO<sub>4<\/sub>)<sub>3<\/sub> Micro\/Nanocompounds for Sodium\u2010Ion Battery Electrodes: A New Insight into Their Electronic and Geometric Structure"],"prefix":"10.1002","volume":"21","author":[{"given":"Weifeng","family":"Huang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biao","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muhammad Farooq","family":"Saleem","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianjian","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingguo","family":"Xia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wangsheng","family":"Chu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyu","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,11,4]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1110464"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40914g"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201200803"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.3442365"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja312044k"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm400805q"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3038646"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr3001862"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm1015614"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic101130m"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40847g"},{"key":"e_1_2_6_12_2","first-page":"1100","volume":"40","author":"Fisher D. 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