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In contrast, reaction of Pt analogues with SnCl\n                    <jats:sub>2<\/jats:sub>\n                    leads to Pt\uf8ffCl bond activation, resulting in methylplatinum species\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010[PtMe{(P^N)\n                    <jats:sub>2<\/jats:sub>\n                    SnCl\n                    <jats:sub>2<\/jats:sub>\n                    }][BF\n                    <jats:sub>4<\/jats:sub>\n                    ]. Over time, they isomerise to methylstannylene species, indicating that both kinetic and thermodynamic products can be isolated for Pt, whereas for Pd only methylstannylene complexes are isolated. Oxidative addition of RSnCl\n                    <jats:sub>3<\/jats:sub>\n                    (R=Me, Bu, Ph) to M\n                    <jats:sup>0<\/jats:sup>\n                    precursors (M=Pd or Pt) in the presence of P^N ligands results in diphosphinostannylene pincer complexes\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010[MCl{(P^N)\n                    <jats:sub>2<\/jats:sub>\n                    SnCl(R)}][SnCl\n                    <jats:sub>4<\/jats:sub>\n                    R], which are structurally similar to the products from SnCl\n                    <jats:sub>2<\/jats:sub>\n                    insertion. This showed that addition of RSnCl\n                    <jats:sub>3<\/jats:sub>\n                    to M\n                    <jats:sup>0<\/jats:sup>\n                    results in formal Sn\uf8ffCl bond oxidative addition. A probable pathway of activation of the tin reagents and formation of different products is proposed and the relevancy of the findings for Pd and Pt catalysed processes that use SnCl\n                    <jats:sub>2<\/jats:sub>\n                    as a co\u2010catalyst is discussed.\n                  <\/jats:p>","DOI":"10.1002\/chem.201404071","type":"journal-article","created":{"date-parts":[[2014,11,25]],"date-time":"2014-11-25T14:49:55Z","timestamp":1416926995000},"page":"1765-1779","source":"Crossref","is-referenced-by-count":25,"title":["Intramolecularly Stabilised Group\u200510 Metal Stannyl and Stannylene Complexes: Multi\u2010pathway Synthesis and Observation of Platinum\u2010to\u2010Tin Alkyl Transfer"],"prefix":"10.1002","volume":"21","author":[{"given":"Stefan","family":"Warsink","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric J.","family":"Derrah","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cornelis A.","family":"Boon","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yves","family":"Cabon","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeroen J. 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