{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T13:54:24Z","timestamp":1792072464760,"version":"4.4.0"},"reference-count":68,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2014,10,8]],"date-time":"2014-10-08T00:00:00Z","timestamp":1412726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"crossref","award":["2013R1A2A2A01007176"],"award-info":[{"award-number":["2013R1A2A2A01007176"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The adsorptive removal of organoarsenic compounds such as <jats:italic>p<\/jats:italic>\u2010arsanilic acid (ASA) and roxarsone (ROX) from water using metal\u2013organic frameworks (MOFs) has been investigated for the first time. A MOF, iron benzenetricarboxylate (also called MIL\u2010100\u2010Fe) exhibits a much higher adsorption capacity for ASA and ROX than activated carbon, zeolite (HY), goethite, and other MOFs. The adsorption of ASA and ROX over MIL\u2010100\u2010Fe is also much more rapid than that over activated carbon. Moreover, the used MIL\u2010100\u2010Fe can be recycled by simply washing with acidic ethanol. Therefore, it is determined that a MOF such as MIL\u2010100\u2010Fe can be used to remove organoarsenic compounds from contaminated water because of its high adsorption capacity, rapid adsorption, and ready regeneration. Moreover, only one of three analogous MIL\u2010100 species (MIL\u2010100\u2010Fe, rather than MIL\u2010100\u2010Al or MIL\u2010100\u2010Cr) can effectively remove the organoarsenic compounds. This selective and high adsorption over MIL\u2010100\u2010Fe, different from other analogous MIL\u2010100 species, can be explained (through calculations) by the facile desorption of water from MIL\u2010100\u2010Fe as well as the large (absolute value) replacement energy (difference between the adsorption energies of the organoarsenic compounds and water) exhibited by MIL\u2010100\u2010Fe. A plausible adsorption\/desorption mechanism is proposed based on the surface charge of the MOFs, FTIR results, calculations, and the reactivation results with respect to the solvents used in the experiments.<\/jats:p>","DOI":"10.1002\/chem.201404658","type":"journal-article","created":{"date-parts":[[2014,10,8]],"date-time":"2014-10-08T15:43:09Z","timestamp":1412782989000},"page":"347-354","source":"Crossref","is-referenced-by-count":177,"title":["Effect of Central Metal Ions of Analogous Metal\u2013Organic Frameworks on Adsorption of Organoarsenic Compounds from Water: Plausible Mechanism of Adsorption and Water Purification"],"prefix":"10.1002","volume":"21","author":[{"given":"Jong Won","family":"Jun","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minman","family":"Tong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beom K.","family":"Jung","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zubair","family":"Hasan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chongli","family":"Zhong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sung Hwa","family":"Jhung","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,10,8]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2012.05.078"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2012.03.064"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2014.01.003"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2013.09.040"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/s13762-013-0261-9"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2011.02.040"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/es803178f"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/es071752x"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20110162"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1JM14101E"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60059a"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1166\/apm.2013.1005"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400005f"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/B618320B"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200216x"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00006D"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906034k"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105113"},{"key":"e_1_2_6_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105113"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC04759G"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201100050"},{"key":"e_1_2_6_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201100050"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic402012d"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta11807j"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.09.035"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp507074x"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200601604"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2013.08.110"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2014.02.070"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp01703e"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2012.01.005"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1116275"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200801130"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0276974"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/b927113a"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm901983a"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2011.11.025"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460592"},{"key":"e_1_2_6_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460592"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2010.05.018"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/B704325B"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2012.02.027"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ce25760b"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2005.10.040"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2007.03.055"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2008.03.028"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2008.09.003"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.12.005"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2012.11.011"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1166\/apm.2013.1002"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2013.06.076"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja403571z"},{"key":"e_1_2_6_51_2","unstructured":"As to the adsorption energy of water on MIL\u2010101\u2010Cr in our calculations the clusters were saturated with hydrogen atoms and in this case MIL\u2010101\u2010Cr has a cluster identical with that of MIL\u2010100\u2010Cr. Therefore we did additional calculations with the clusters saturated with CH3groups to distinguish the two MOFs and the adsorption energies for the two MOFs are quite close with \u221279.0\u2005kJ\u2009mol\u22121for MIL\u2010100\u2010Cr and \u221279.8\u2005kJ\u2009mol\u22121for MIL\u2010101\u2010Cr. Therefore the adsorption energies of the two MOFs are similar to each other."},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705998"},{"key":"e_1_2_6_52_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200705998"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/la800227x"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01506g"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/es061160z"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/es0486770"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/es048701"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm16030g"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902382"},{"key":"e_1_2_6_60_2","unstructured":"Accelrys Inc.Materials Studio 3.0\u2005V.; Accelrys Inc: San Diego CA 2003."},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/la904502h"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp809408x"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm300863c"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp402916y"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201404658","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201404658","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:50:55Z","timestamp":1760302255000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201404658"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,10,8]]},"references-count":68,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2015,1,2]]}},"alternative-id":["10.1002\/chem.201404658"],"URL":"https:\/\/doi.org\/10.1002\/chem.201404658","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,10,8]]}}}