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The low thermal stability of these compounds can be increased using phosphites instead of phosphines as coligands. Through an amalgam reduction of [MoCl<jats:sub>3<\/jats:sub>(PCP)] in the presence of trimethyl phosphite and N<jats:sub>2<\/jats:sub> the highly activated and room\u2010temperature stable dinitrogen complex [Mo(N<jats:sub>2<\/jats:sub>)(PCP)(P(OMe)<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] is obtained. 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