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The azide\/chloride exchange in CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> as well as the formation of tetrazolate salts in CH<jats:sub>3<\/jats:sub>CN solutions of the polyazido mercurates were investigated. Single crystal X\u2010ray structures of all new compounds, and for comparison [Ph<jats:sub>4<\/jats:sub>P][Cd<jats:sub>2<\/jats:sub>(N<jats:sub>3<\/jats:sub>)<jats:sub>5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)], were determined. Moreover, the synthesis of anhydrous cadmium(II) azide and its DMSO adduct is presented for the first time. For a better understanding of structure and bonding in E(N<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>, [E(N<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> and [E(N<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>, theoretical calculations at the M06\u20102X\/aug\u2010cc\u2010pVDZ level were carried out.<\/jats:p>","DOI":"10.1002\/chem.201406023","type":"journal-article","created":{"date-parts":[[2015,1,22]],"date-time":"2015-01-22T14:58:55Z","timestamp":1421938735000},"page":"3649-3663","source":"Crossref","is-referenced-by-count":16,"title":["Binary Polyazides of Cadmium and Mercury"],"prefix":"10.1002","volume":"21","author":[{"given":"Axel","family":"Schulz","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,1,22]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199505111"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951070504"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201300162"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.189002302232"},{"key":"e_1_2_6_5_2","first-page":"744","volume":"11","author":"Berthelot M.","year":"1894","journal-title":"Bull. 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