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In contrast, relatively few methods are available for the synthesis of homoallylic alcohols through coupling of vinylcyclopropanes (VCPs) with aldehydes, even with transition\u2010metal catalysts. Here, we report that the hydrostannation of vinylcyclopropanes (VCPs) was effectively promoted by dibutyliodotin hydride (Bu<jats:sub>2<\/jats:sub>SnIH). The resultant allylic tin compounds reacted easily with aldehydes. Furthermore, the use of Bu<jats:sub>2<\/jats:sub>SnIH was effectively catalytic in the presence of hydrosilane as a hydride source, which established a coupling reaction of VCPs with aldehydes for the synthesis of homoallylic alcohols without the use of transition\u2010metal catalysts. In contrast to conventional catalytic reactions of VCPs, the presented method allowed the use of several VCPs in addition to conventional donor\u2013acceptor cyclopropanes.<\/jats:p>","DOI":"10.1002\/chem.201406496","type":"journal-article","created":{"date-parts":[[2015,3,5]],"date-time":"2015-03-05T15:28:45Z","timestamp":1425569325000},"page":"6295-6300","source":"Crossref","is-referenced-by-count":20,"title":["Transition\u2010Metal\u2010Free Coupling Reaction of Vinylcyclopropanes with Aldehydes Catalyzed by Tin 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