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The new PODIPY and aza\u2010PODIPY dyes are found to have photophysical properties. PODIPY and aza\u2010PODIPY are water\u2010soluble, and aza\u2010PODIPY is suited for labeling living Hep\u20102 cells for imaging assays in the near\u2010infrared region. Molecular orbital calculations show that the increase in the HOMO\u2013LUMO band gap for the lowest energy absorption bands is observed in the new phosphorus\u2010containing aza\u2010PODIPY, and the HOMO and LUMO energies of aza\u2010PODIPY are found to be higher than those of aza\u2010BODIPY.\n                  <\/jats:p>","DOI":"10.1002\/chem.201406535","type":"journal-article","created":{"date-parts":[[2015,3,4]],"date-time":"2015-03-04T15:09:41Z","timestamp":1425481781000},"page":"6079-6082","source":"Crossref","is-referenced-by-count":78,"title":["A New Water\u2010Soluble Phosphorus\u2010Dipyrromethene and Phosphorus\u2010Azadipyrromethene Dye: PODIPY\/aza\u2010PODIPY"],"prefix":"10.1002","volume":"21","author":[{"given":"Xin\u2010Dong","family":"Jiang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiuli","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongmei","family":"Xi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haifeng","family":"Yu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Guan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang\u2010Liang","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin\u2010Jiu","family":"Xiao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,3,4]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr078381n"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702070"},{"key":"e_1_2_3_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200702070"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60411J"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00030G"},{"key":"e_1_2_3_6_2","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077756j"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200801906"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol2014076"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902527"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol902631d"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol500572t"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4034622"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/b513878g"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo060984w"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CP22396H"},{"key":"e_1_2_3_17_2","unstructured":"\u00a0"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b814586e"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/b820461f"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353520"},{"key":"e_1_2_3_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353520"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt30618b"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja038763k"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1233701"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50493j"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/b820141b"},{"key":"e_1_2_3_26_2","unstructured":"\u00a0"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic101694z"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt12316a"},{"key":"e_1_2_3_29_2","unstructured":"\u00a0"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061581h"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic7016159"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja203382q"},{"key":"e_1_2_3_33_2","unstructured":"\u00a0"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400868w"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2001924"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja904470m"},{"key":"e_1_2_3_37_2","unstructured":"For 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