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In the exploration of an asymmetric variant, chiral sulfinylphosphine ligands proved advantageous in controlling stereochemistry of B\uf8ffCu addition and in promoting transmetalation of enantioenriched alkyl\uf8ffCu species. The stereochemical outcome supported a sequential <jats:italic>syn<\/jats:italic>\u2010borylcupration and configuration\u2010retentive transmetalation mechanism. Moreover, \u03b1\u2010chiral \u03b2\u2010borylstannanes were easily transformed into a diverse array of secondary alkylstannanes and triarylethane with high enantiomeric purity. The applications of chiral sulfinylphosphine ligands to other tandem Cu\uf8ffB addition reactions are currently under investigation in our group.<\/jats:p>","DOI":"10.1002\/chem.201500060","type":"journal-article","created":{"date-parts":[[2015,2,12]],"date-time":"2015-02-12T11:52:34Z","timestamp":1423741954000},"page":"4918-4922","source":"Crossref","is-referenced-by-count":57,"title":["Copper\u2010Catalyzed Asymmetric Three\u2010Component Borylstannation: Enantioselective Formation of C\uf8ffSn 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