{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T13:56:07Z","timestamp":1775310967212,"version":"3.50.1"},"reference-count":91,"publisher":"Wiley","issue":"34","license":[{"start":{"date-parts":[[2015,7,15]],"date-time":"2015-07-15T00:00:00Z","timestamp":1436918400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,8,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>[Fe(tvp)<jats:sub>2<\/jats:sub>(NCS)<jats:sub>2<\/jats:sub>] (<jats:bold>1<\/jats:bold>) (tvp=<jats:italic>trans<\/jats:italic>\u2010(4,4\u2032\u2010vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two\u2010dimensional grids. This uncommon supramolecular conformation defines square\u2010sectional nanochannels (diagonal\u22482.2\u2005nm) in which inclusion molecules are located. The guest\u2010loaded framework <jats:bold>1@guest<\/jats:bold> displays complete thermal spin\u2010crossover (SCO) behavior with the characteristic temperature <jats:italic>T<\/jats:italic><jats:sub>1\/2<\/jats:sub> dependent on the guest molecule, whereas the guest\u2010free species <jats:bold>1<\/jats:bold> is paramagnetic whatever the temperature. For the benzene\u2013guest derivatives, the characteristic SCO temperature <jats:italic>T<\/jats:italic><jats:sub>1\/2<\/jats:sub> decreases as the Hammet <jats:italic>\u03c3<\/jats:italic><jats:sub>p<\/jats:sub> parameter increases. In general, the <jats:bold>1@guest<\/jats:bold> series shows large entropy variations associated with the SCO and conformational changes of the interpenetrated grids that leads to a crystallographic\u2010phase transition when the guest is benzonitrile or acetonitrile\/H<jats:sub>2<\/jats:sub>O.<\/jats:p>","DOI":"10.1002\/chem.201500310","type":"journal-article","created":{"date-parts":[[2015,7,15]],"date-time":"2015-07-15T09:03:21Z","timestamp":1436951001000},"page":"12112-12120","source":"Crossref","is-referenced-by-count":28,"title":["Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two\u2010Dimensional Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"21","author":[{"given":"Tania","family":"Romero\u2010Morcillo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Noelia","family":"De\u2005la\u2005Pinta","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lorena M.","family":"Callejo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Luc\u00eda","family":"Pi\u00f1eiro\u2010L\u00f3pez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. Carmen","family":"Mu\u00f1oz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gotzon","family":"Madariaga","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sacramento","family":"Ferrer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tomasz","family":"Breczewski","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roberto","family":"Cort\u00e9s","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9 A.","family":"Real","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,7,15]]},"reference":[{"key":"e_1_2_7_1_2","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1070967"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b305705b"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201400806"},{"key":"e_1_2_7_5_2","unstructured":"For example see:"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80430-0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/BFb0111269"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00067a003"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1080\/02603599508035780"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-53499-7_2"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199420241"},{"key":"e_1_2_7_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941062006"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar020242z"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(02)00220-5"},{"key":"e_1_2_7_14_2","unstructured":"Top. 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