{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:37:13Z","timestamp":1786977433819,"version":"build-2736575974"},"reference-count":55,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2015,6,19]],"date-time":"2015-06-19T00:00:00Z","timestamp":1434672000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,7,20]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The treatment of bis[(dialkylamino)cyclopropenimines] with dihalophosphines in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) to form diimine\u2010stabilized P\n                    <jats:sup>III<\/jats:sup>\n                    \u2010centered dications is reported. The structures of the new compounds were determined by using X\u2010ray diffraction analysis and their donor abilities as ligands evaluated through electrochemical methods. Despite the two positive charges that they bear, these compounds depict intermediate behavior between that of phosphines and phosphites. The coordination of the [L\n                    <jats:sub>2<\/jats:sub>\n                    PR]\n                    <jats:sup>2+<\/jats:sup>\n                    moiety to Au\n                    <jats:sup>I<\/jats:sup>\n                    and Ag\n                    <jats:sup>I<\/jats:sup>\n                    is also reported. Even more surprisingly, these phosphorus centers can be oxidized to the corresponding P\n                    <jats:sup>V<\/jats:sup>\n                    dications in the presence of strong oxidants such as peroxides or XeF\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/chem.201500688","type":"journal-article","created":{"date-parts":[[2015,6,20]],"date-time":"2015-06-20T04:25:01Z","timestamp":1434774301000},"page":"10829-10834","source":"Crossref","is-referenced-by-count":23,"title":["Bis[(dialkylamino)cyclopropenimine]\u2010Stabilized P\n                    <sup>III<\/sup>\n                    \u2010 and P\n                    <sup>V<\/sup>\n                    \u2010Centered Dications"],"prefix":"10.1002","volume":"21","author":[{"given":"\u00c1gnes","family":"Kozma","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00f6rg","family":"Rust","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuel","family":"Alcarazo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,6,19]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp990511b"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/poc.666"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200500054"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200906168"},{"key":"e_1_2_6_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200906168"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3015764"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja407277a"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0033-1338516"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201302959"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)80248-3"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2013.10.007"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201407809"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201407809"},{"key":"e_1_2_6_14_2","unstructured":"During the last years our group has been very actively working on the design of mono\u2010 or polycationic phosphines depicting excellent \u03c0\u2010acceptor properties see:"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja210223s"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201100338"},{"key":"e_1_2_6_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201100338"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja306947m"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CC36225B"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja411146x"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303686"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402375"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199905)625:5<729::AID-ZAAC729>3.0.CO;2-D"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200700590"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800157"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic201342z"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1NJ20808J"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic3006508"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1991-26682"},{"key":"e_1_2_6_29_2","unstructured":"For structurally characterized dicationic phosphanes see ref.\u2005[6\u2009e] and:"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/hc.520060415"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic026090l"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710923g"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106172d"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402636"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00739a057"},{"key":"e_1_2_6_36_2","unstructured":"For a previous synthesis of8see ref.\u2005[3\u2009d]."},{"key":"e_1_2_6_37_2","unstructured":"CCDC\u20051048789 1048790 1048791 1048792 1048793 1048794 1048796 1048797 1048798 and 1048799contain the supplementary crystallographic data for this paper. 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