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The size of the AgSbS<jats:sub>2<\/jats:sub> NCs can be tuned from 5.3 to 58.3\u2005nm with narrow size distributions by selection of appropriate precursors and fine control of the experimental conditions. Over 15\u2005g of high\u2010quality AgSbS<jats:sub>2<\/jats:sub> NCs can be obtained from one single reaction, indicative of the up\u2010scalability of the present synthesis. The resulting NCs display strong absorptions in the visible\u2010to\u2010NIR range and exceptional air stability. The photoelectrochemical measurements indicate that, although the pristine AgSbS<jats:sub>2<\/jats:sub> NC electrodes generate a cathodic photocurrent with a relatively small photocurrent density and poor stability, both of them can be significantly improved subject to CdS surface modification, showing promise in solar energy conversion applications.<\/jats:p>","DOI":"10.1002\/chem.201501000","type":"journal-article","created":{"date-parts":[[2015,6,20]],"date-time":"2015-06-20T04:26:27Z","timestamp":1434774387000},"page":"11143-11151","source":"Crossref","is-referenced-by-count":39,"title":["Monodisperse AgSbS<sub>2<\/sub> Nanocrystals: Size\u2010Control Strategy, Large\u2010Scale Synthesis, and Photoelectrochemistry"],"prefix":"10.1002","volume":"21","author":[{"given":"Bin","family":"Zhou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingrun","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihui","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chi","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Hua","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Can","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,6,19]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3118"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1117908"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1209845"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/370354a0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01217"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2083398"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja308936b"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja207159j"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja211952z"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004398"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201004398"},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201403281"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.4898635"},{"key":"e_1_2_6_17_2","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/35003535"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0173167"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020703)41:13<2368::AID-ANIE2368>3.0.CO;2-G"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020703)114:13<2474::AID-ANGE2474>3.0.CO;2-#"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn5018654"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja710004h"},{"key":"e_1_2_6_23_2","unstructured":"\u00a0"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja805845q"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl901538w"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn401274e"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3057985"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302867"},{"key":"e_1_2_6_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302867"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja400452t"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja501591n"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja402702x"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC06071G"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404220"},{"key":"e_1_2_6_34_2","unstructured":"\u00a0"},{"key":"e_1_2_6_35_2","first-page":"336","volume":"4","author":"Torimoto T.","year":"2013","journal-title":"J. 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