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In the presence of 2.5\u2005mol\u2009% of Rh<jats:sup>I<\/jats:sup>\/<jats:bold>L2<\/jats:bold>, enantioenriched conjugate addition adducts were isolated in 72\u201399\u2009% yields with 86\u201398\u2009%\u2005<jats:italic>ee<\/jats:italic>. This protocol offers a convenient method to access a variety of 3\u2010arylsuccinimides in a highly enantioselective manner. Maleimides with readily cleavable <jats:italic>N<\/jats:italic>\u2010protecting groups were tolerated enabling the synthesis of useful synthetic intermediates. 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