{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,17]],"date-time":"2026-03-17T20:20:38Z","timestamp":1773778838403,"version":"3.50.1"},"reference-count":86,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2015,7,23]],"date-time":"2015-07-23T00:00:00Z","timestamp":1437609600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","award":["GRK1782"],"award-info":[{"award-number":["GRK1782"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,8,24]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Systematic experimental and theoretical investigations of reactions of R<jats:sup>1<\/jats:sup>SnCl<jats:sub>3<\/jats:sub> (R<jats:sup>1<\/jats:sup>=CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>C(Me)O) with (Me<jats:sub>3<\/jats:sub>Si)<jats:sub>2<\/jats:sub>Te allowed for the stepwise formation and single\u2010crystalline isolation of the first tin sesquitelluride clusters with functional organic ligands. Subsequent derivatization of the latter took place under reorganization of the inorganic core, affording clusters with complex hybrid architectures.<\/jats:p>","DOI":"10.1002\/chem.201501666","type":"journal-article","created":{"date-parts":[[2015,7,24]],"date-time":"2015-07-24T16:03:39Z","timestamp":1437753819000},"page":"12376-12388","source":"Crossref","is-referenced-by-count":27,"title":["Synthesis and Thorough Investigation of Discrete Organotin Telluride Clusters"],"prefix":"10.1002","volume":"21","author":[{"given":"Jens P.","family":"Eu\u00dfner","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ralph O.","family":"Kusche","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stefanie","family":"Dehnen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,7,23]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00071a034"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic980574t"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT02252A"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310455"},{"key":"e_1_2_6_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310455"},{"key":"e_1_2_6_6_2","unstructured":"\u00a0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.19960080103"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1142535"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja074481z"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1170524"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/nphys2442"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.3267"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200601763"},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1515\/znb-1983-0805","volume":"38","author":"Eisenmann B.","year":"1983","journal-title":"Z. Naturforsch. Teil B"},{"key":"e_1_2_6_16_2","doi-asserted-by":"crossref","first-page":"318","DOI":"10.1515\/ncrs-2000-0305","volume":"215","author":"Evenson C. R.","year":"2000","journal-title":"Z. Kristallogr. New Cryst. Struct."},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010242f"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic801762h"},{"key":"e_1_2_6_19_2","unstructured":"\u00a0"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic300075a"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610833D"},{"key":"e_1_2_6_22_2","unstructured":"\u00a0"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199108341"},{"key":"e_1_2_6_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030733"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm980247j"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)00707-0"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1107\/S1600536810025729"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201300271"},{"key":"e_1_2_6_28_2","unstructured":"\u00a0"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1994-0508"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426500108546553"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/om101049d"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc32615a"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic502026g"},{"key":"e_1_2_6_34_2","unstructured":"\u00a0"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/CC9960000505"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9906159"},{"key":"e_1_2_6_37_2","unstructured":"\u00a0"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200751g"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107666"},{"key":"e_1_2_6_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107666"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203573"},{"key":"e_1_2_6_41_2","unstructured":"\u00a0"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900523"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201200155"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05666C"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic502627h"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301521"},{"key":"e_1_2_6_47_2","unstructured":"\u00a0"},{"key":"e_1_2_6_48_2","unstructured":"TURBOMOLE Version\u20056.2 TURBOMOLE GmbH 2011. TURBOMOLE is a development of University of Karlsruhe and Forschungszentrum Karlsruhe 1989\u20132007; Ridft program:"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(95)00838-U"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1007\/s002140050244"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1305880"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00440-X"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(96)01343-7"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(02)00975-2"},{"key":"e_1_2_6_58_2","doi-asserted-by":"crossref","unstructured":"F. Furche D. Rappoport Computational and Theoretical Chemistry Vol.\u200516(Ed.: M. Olivucci) Elsevier Amsterdam 2005 pp.\u200593\u2013138; Escf program:","DOI":"10.1016\/S1380-7323(05)80020-2"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.471637"},{"key":"e_1_2_6_60_2","unstructured":"HRMS (ESI) calcd for [C18H33O3Sn3Te4]+:m\/z=1164.5688; found: 1164.5713."},{"key":"e_1_2_6_61_2","unstructured":"The reductive elimination of organic ligands was also discussed for the generation of [(R1 \u20092Sn)3Se4][SnCl3] (see ref.\u2005[11])."},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic100700f"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC03727C"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8090388"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800987"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270192008400"},{"key":"e_1_2_6_67_2","unstructured":"\u00a0"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)83631-1"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00031a054"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100785a001"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002371"},{"key":"e_1_2_6_72_2","unstructured":"The N atoms still occupy the \u201ctrans\u201d positions of a pseudo trigonal bipyramidal coordination arrangement (N1\u2010Sn1\u2010Te1: 168.7(1)\u00b0 N3\u2010Sn2\u2010Te1: 173.1(1)\u2009\u00b0). Though C\u22c5\u22c5\u22c5Sn distances of theipsoC atoms of C1 and C13 are shorter than 3.1\u2005\u00c5 resulting in coordination polyhedra with a higher number of vertices."},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201200292"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9840001349"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)01069-5"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1139\/v86-164"},{"key":"e_1_2_6_77_2","unstructured":"The bond energies were calculated according to Equations\u2005(3) and (4) in the Supporting Information."},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.449486"},{"key":"e_1_2_6_79_2","unstructured":"Eonset(1)=2.6\u2005eV Eonset(2)=2.1\u2005eV Eonset(3)=1.9\u2005eV."},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)93543-5"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19610730207"},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19633210507"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201501666","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201501666","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:21:04Z","timestamp":1760296864000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201501666"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,7,23]]},"references-count":86,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2015,8,24]]}},"alternative-id":["10.1002\/chem.201501666"],"URL":"https:\/\/doi.org\/10.1002\/chem.201501666","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,7,23]]}}}