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Here, we reported a family of MFI\u2010type metallosilicate zeolites, AeS\u20101 (Ae: alkaline\u2010earth metal ions of Mg, Ca, Sr or Ba; S\u20101: silicalite\u20101) through a direct one\u2010pot hydrothermal method involving the acidic co\u2010hydrolysis\/condensation of the silica precursor with the Ae salts. Step\u2010by\u2010step full characterizations were designed and conducted for in\u2010depth discussion of the Ae status in AeS\u20101. Strong basicity (<jats:italic>H<\/jats:italic>_\u224822.5\u201326.5) was detected in AeS\u20101. The basicity was further confirmed by CO<jats:sub>2<\/jats:sub> sorption measurements, <jats:sup>13<\/jats:sup>C\u2005NMR spectra of chloroform\u2010adsorbed samples, and <jats:sup>1<\/jats:sup>H\u2192<jats:sup>13<\/jats:sup>C and <jats:sup>1<\/jats:sup>H\u2192<jats:sup>29<\/jats:sup>Si cross\u2010polarization magic\u2010angle spinning NMR spectra of ethyl cyanoacetate\u2010adsorbed samples. The results of Knoevenagel condensations demonstrated the excellent solid base catalysis of AeS\u20101, which showed high activity, reusability, and shape\u2010selectivity, all of which are explained by Ae\u2010derived zeolitic intracrystalline strong basic sites.<\/jats:p>","DOI":"10.1002\/chem.201501894","type":"journal-article","created":{"date-parts":[[2015,9,2]],"date-time":"2015-09-02T16:49:59Z","timestamp":1441212599000},"page":"15412-15420","source":"Crossref","is-referenced-by-count":27,"title":["One\u2010Pot Synthesis of Zeolitic Strong Solid Bases: A Family of Alkaline\u2010Earth Metal\u2010Containing 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