{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,28]],"date-time":"2025-10-28T05:52:17Z","timestamp":1761630737245,"version":"build-2065373602"},"reference-count":102,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2015,10,20]],"date-time":"2015-10-20T00:00:00Z","timestamp":1445299200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"crossref","award":["LE110100141"],"award-info":[{"award-number":["LE110100141"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,11,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The novel phosphonyl\u2010substituted ferrocene derivatives [Fe(\u03b7<jats:sup>5<\/jats:sup>\u2010Cp)(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>{P(O)(O\u2010<jats:italic>i<\/jats:italic>Pr)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>\u20101,2)] (<jats:bold>Fc<jats:sup>1,2<\/jats:sup><\/jats:bold>) and [Fe{\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>P(O)(O\u2010<jats:italic>i<\/jats:italic>Pr)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>] (<jats:bold>Fc<jats:sup>1,1\u2032<\/jats:sup><\/jats:bold>) react with SnCl<jats:sub>2<\/jats:sub>, SnCl<jats:sub>4<\/jats:sub>, and SnPh<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, giving the corresponding complexes [(Fc<jats:sup>1,2<\/jats:sup>)<jats:sub>2<\/jats:sub>SnCl][SnCl<jats:sub>3<\/jats:sub>] (<jats:bold>1<\/jats:bold>), [{(Fc<jats:sup>1,1\u2032<\/jats:sup>)SnCl<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>] (<jats:bold>2<\/jats:bold>), [(Fc<jats:sup>1,1\u2032<\/jats:sup>)SnCl<jats:sub>4<\/jats:sub>] (<jats:bold>3<\/jats:bold>), [{(Fc<jats:sup>1,1\u2032<\/jats:sup>)SnPh<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>] (<jats:bold>4<\/jats:bold>), and [(Fc<jats:sup>1,2<\/jats:sup>)SnCl<jats:sub>4<\/jats:sub>] (<jats:bold>5<\/jats:bold>), respectively. The compounds are characterized by elemental analyses, <jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>31<\/jats:sup>P, <jats:sup>119<\/jats:sup>Sn NMR and IR spectroscopy, <jats:sup>31<\/jats:sup>P and <jats:sup>119<\/jats:sup>Sn CP\u2010MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single\u2010crystal as well as powder X\u2010ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of <jats:bold>Fc<jats:sup>1,1\u2032<\/jats:sup><\/jats:bold> and <jats:bold>Fc<jats:sup>1,2<\/jats:sup><\/jats:bold> towards tin(II) chloride.<\/jats:p>","DOI":"10.1002\/chem.201501999","type":"journal-article","created":{"date-parts":[[2015,10,20]],"date-time":"2015-10-20T10:58:26Z","timestamp":1445338706000},"page":"16609-16622","source":"Crossref","is-referenced-by-count":26,"title":["Different Complexation Behavior of P\u2010Functionalized Ferrocene Derivatives Towards SnCl<sub>2<\/sub>, SnCl<sub>4<\/sub> and SnPh<sub>2<\/sub>Cl<sub>2<\/sub>: Auto\u2010ionization and Redox\u2010Type Reactions"],"prefix":"10.1002","volume":"21","author":[{"given":"Matthias","family":"Gawron","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christina","family":"Dietz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Lutter","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrew","family":"Duthie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Viatcheslav","family":"Jouikov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Klaus","family":"Jurkschat","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,10,20]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301477"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900093s"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199013971"},{"key":"e_1_2_6_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19901021225"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102261"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja961910c"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980153j"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400082t"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)00358-3"},{"key":"e_1_2_6_11_2","unstructured":"\u00a0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja211135s"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201101938"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0200747"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201300677"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00893-7"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400186m"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700365p"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)00112-X"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199411561"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941061120"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.876"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00388C"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200017h"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(01)00358-9"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/b110770b"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200700233"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT01912E"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800294"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300563g"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50743b"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9860001543"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.12.023"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic3006713"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)80571-9"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/om050074p"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(02)01651-0"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50995h"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980754a"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2014.04.035"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)00908-1"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/om900435y"},{"key":"e_1_2_6_42_2","unstructured":"\u00a0"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(01)00584-9"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/B205942H"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(01)00379-6"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/a904016a"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10920k"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(97)06129-X"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2011.03.027"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270196001758"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1524\/ncrs.1998.213.14.259"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/om4004797"},{"key":"e_1_2_6_53_2","unstructured":"\u00a0"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0523704"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob25187f"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1139\/v08-113"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/om991013s"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/a808918c"},{"key":"e_1_2_6_59_2","first-page":"116","volume":"12","author":"Kim T.\u2010J.","year":"1991","journal-title":"Bull. Korean Chem. Soc."},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(95)01161-A"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1039\/b403862b"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.09.042"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic1016164"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200600319"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200600771"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2010.06.061"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2005.07.018"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199906)625:6<845::AID-ZAAC845>3.0.CO;2-F"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/om058028c"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01367f"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901421"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.05.031"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060355c"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/b801115j"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2005.10.024"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2009.04.035"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.590090104"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)87112-4"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(96)06246-8"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.5796\/kogyobutsurikagaku.65.149"},{"key":"e_1_2_6_81_2","first-page":"163","volume":"8","author":"Kolotii A.","year":"1963","journal-title":"Zh. Neorg. Khim."},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(01)93511-1"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-3160(00)35013-4"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/0471758078"},{"key":"e_1_2_6_85_2","first-page":"49","volume-title":"Organic Electrochemistry","author":"Amatore C.","year":"2001"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2005.12.026"},{"first-page":"8.136","volume-title":"Lange\u2019s Handbook of Chemistry","year":"1999","key":"e_1_2_6_87_2"},{"key":"e_1_2_6_88_2","first-page":"818","volume-title":"Inorganic chemistry","author":"Shriver D. F.","year":"1994"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1201\/9781420007282"},{"volume-title":"Atoms in Molecules: A Quantum Theory","year":"1994","author":"Bader R. F. W.","key":"e_1_2_6_90_2"},{"volume-title":"Physico\u2010chemical properties of non\u2010aqueous solutions of electrolytes","year":"1989","author":"Karapetyan Y. A.","key":"e_1_2_6_91_2"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9904009"},{"key":"e_1_2_6_93_2","first-page":"905","volume-title":"Inorganic Chemistry","author":"Wiberg N.","year":"2001"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.2096639"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(93)80253-6"},{"key":"e_1_2_6_96_2","first-page":"403","volume-title":"Electrochemical Reactions in Nonaqueous Systems","author":"Mann C. K.","year":"1970"},{"key":"e_1_2_6_97_2","unstructured":"Gaussian 03 Revision B.01 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman J.\u2005A. Montgomery T. Vreven K.\u2005N. Kudin J.\u2005C. Burant J.\u2005M. Millam S.\u2005S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G.\u2005A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J.\u2005E. Knox H.\u2005P. Hratchian J.\u2005B. Cross C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski P.\u2005Y. Ayala K. Morokuma G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg V.\u2005G. Zakrzewski S. Dapprich A.\u2005D. Daniels M.\u2005C. Strain O. Farkas D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J.\u2005V. Ortiz Q. Cui A.\u2005B. Baboul S. Clifford J. Cioslowski B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010 Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez J.\u2005A. Pople Gaussian Inc. Pittsburgh PA 2003."},{"key":"e_1_2_6_98_2","unstructured":"AIMAll (Version 15.05.18) T.\u2005A. Keith TK Gristmill Software Overland Park KS USA 2015."},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201501999","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201501999","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201501999","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201501999","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T11:42:41Z","timestamp":1760269361000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201501999"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,10,20]]},"references-count":102,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2015,11,9]]}},"alternative-id":["10.1002\/chem.201501999"],"URL":"https:\/\/doi.org\/10.1002\/chem.201501999","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2015,10,20]]}}}